Organocuprates (Gilman Reagents)

We've seen organometallic reagents featuring magnesium, as well as lithium, so how about copper? These are called organocuprates, or sometimes Gilman reagents. What do they look like? How do we make them? What do we do? Let's take a look!
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Пікірлер: 17

  • @TheGemar14
    @TheGemar142 жыл бұрын

    One other important reaction: Gilman reagents only add once to acid chlorides to form the ketone whereas Grignards and organolithiums add twice to form the alcohol

  • @lauraschonborn5633
    @lauraschonborn5633 Жыл бұрын

    I am so impressed by your knowledge. you were born to teach. love you xoxo

  • @vegatronld
    @vegatronld4 жыл бұрын

    Good stuff Dave.

  • @natepadol3067
    @natepadol30674 жыл бұрын

    Great video Dave!!! We love how thorough and how amazing you are are at explaining science to our class -the board of Mrs. Kelly’s 6th period class at LFC in Allen, Texas

  • @pjb3194

    @pjb3194

    4 жыл бұрын

    youre in 6th grade learning university level 2nd year organic chemistry?

  • @natepadol3067

    @natepadol3067

    4 жыл бұрын

    @Pierce Bassett 6th period, not 6th grade. we are taking college level science class in high school

  • @NewWesternFront

    @NewWesternFront

    Жыл бұрын

    @@natepadol3067 still, AP only does genchem I and a ittle II no? different program?

  • @emilyconte6757
    @emilyconte67573 жыл бұрын

    Your hair looks great!!!

  • @samueltanner4769
    @samueltanner47692 жыл бұрын

    Nice job

  • @anirudhbhadri5911
    @anirudhbhadri59114 жыл бұрын

    What if the ring is not benzene but cyclohexane

  • @aishubalan6982
    @aishubalan69823 жыл бұрын

    Super Dave sir and please explain about carbenes sir

  • @ProfessorDaveExplains

    @ProfessorDaveExplains

    3 жыл бұрын

    Already finished, coming soon!

  • @aishubalan6982

    @aishubalan6982

    3 жыл бұрын

    Thank you soo much sir waiting

  • @organicchemistry6357
    @organicchemistry63574 жыл бұрын

    What are the limitations of the Gilman reaction? Are there any functional groups that make this reaction impossible?

  • @illidan124825634

    @illidan124825634

    3 жыл бұрын

    It can only perform a conjugate(1,4) addition instead of a direct(1,2) addition on a alpha, beta-unsaturated carbonyl unlike say a Grignard reagent.

  • @babarazamsucks
    @babarazamsucks4 жыл бұрын

    First!

  • @cody967
    @cody9674 жыл бұрын

    First 😂 1116