Organocuprates (Gilman Reagents)
We've seen organometallic reagents featuring magnesium, as well as lithium, so how about copper? These are called organocuprates, or sometimes Gilman reagents. What do they look like? How do we make them? What do we do? Let's take a look!
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One other important reaction: Gilman reagents only add once to acid chlorides to form the ketone whereas Grignards and organolithiums add twice to form the alcohol
I am so impressed by your knowledge. you were born to teach. love you xoxo
Good stuff Dave.
Great video Dave!!! We love how thorough and how amazing you are are at explaining science to our class -the board of Mrs. Kelly’s 6th period class at LFC in Allen, Texas
@pjb3194
4 жыл бұрын
youre in 6th grade learning university level 2nd year organic chemistry?
@natepadol3067
4 жыл бұрын
@Pierce Bassett 6th period, not 6th grade. we are taking college level science class in high school
@NewWesternFront
Жыл бұрын
@@natepadol3067 still, AP only does genchem I and a ittle II no? different program?
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What if the ring is not benzene but cyclohexane
Super Dave sir and please explain about carbenes sir
@ProfessorDaveExplains
3 жыл бұрын
Already finished, coming soon!
@aishubalan6982
3 жыл бұрын
Thank you soo much sir waiting
What are the limitations of the Gilman reaction? Are there any functional groups that make this reaction impossible?
@illidan124825634
3 жыл бұрын
It can only perform a conjugate(1,4) addition instead of a direct(1,2) addition on a alpha, beta-unsaturated carbonyl unlike say a Grignard reagent.
First!
First 😂 1116