Hydride Shift and Methyl Shift Mechanism
leah4sci.com/organic-chemistry/ Presents: Hydride Shift and Alkyl Shift Mechanisms
📺Watch Next: Hydride Shift vs Methyl Shift • Hydride Shift vs Methy...
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Many times in your organic chemistry reactions you will notice that the intermediate carbocation product shifts position. In this video, I explain exactly why and how this shift happens by looking at specific examples and mechanisms explaining both the hydride shift and alkyl/methyl shift phenomenon.
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Пікірлер: 176
6 AM. Been up for 24 hours. OCHEM 1 Exam in 13 hours. I just want you to know that you are a shining light in my deep dark night of studying. Thank you.
@bobslydog
7 жыл бұрын
Leah Fisch I got my A. Worth it!
@zeustheboerboel3794
6 жыл бұрын
Get some sleep man
@SatnamSingh-el2rp
3 жыл бұрын
honestly if you don't cram the couple nights before & just space out your studying for organic chem you'll be much less stressed tbh
@bobslydog
3 жыл бұрын
Satnam Singh lol man I graduated a year ago now. But I appreciate it
@FueledByKass
3 жыл бұрын
@@SatnamSingh-el2rp For real. I never crammed once and always had plenty of time in Orgo. Never pulled all nighters either lmao.
You explain way better than my professor! Go Leah!
@Leah4sci
6 ай бұрын
Aww thanks!
Thank you very much you made the concept easier , you explained it with a lot of patience and every step of the reaction. You inspired me to learn chemistry more seriously
@Leah4sci
5 жыл бұрын
Great to hear that! Glad the video helped. You're welcome. :)
love how much you simplified the concept! thank you!
@Leah4sci
6 ай бұрын
You're so welcome!
Great teachers are a gift. You explain concepts so well. Thanks so much Leah!
@Leah4sci
3 ай бұрын
You're very welcome, I'm happy to help!
Saved my day. These older videos are far superior to the plethora of lectures available online today.
@Leah4sci
3 жыл бұрын
Glad you like it!
thank you! this video was very helpful and made me understand a topic i was very confused with :)
@Leah4sci
Жыл бұрын
Happy to help! You're welcome.
this video helped me way much more than you could ever imagine thank you dear leah
@Leah4sci
4 жыл бұрын
Glad it helped!
GOOD JOB LEAH ! HOPE YOU MAKE MORE OF SUCH SUCCESSFUL VIDEOS AND PEOPLE LIKE IT TOO!!!
@Leah4sci
7 жыл бұрын
Thank you! I'm glad you enjoyed them :)
I never understood hydride shifts until I watched your video. Thank you so much.
@Leah4sci
3 жыл бұрын
You're so welcome!
Thank you. My homework is due in 8 hours and you are the best.
@Leah4sci
6 ай бұрын
Happy to help!
Thank you for making this kind of video. It helps me to understand more about this topic. Wish me luck for my final exam!
@Leah4sci
4 жыл бұрын
Best wishes! And I'm so glad my videos help you to understand the material!
you are amazing.......explained this concept exceptionally well........thank you so much......
@Leah4sci
7 ай бұрын
You're welcome, thanks for the kind words!
I love you. I love you. I love you. I love you. I love you. I love you. I love you. I love you. I can't say it enough. I have an organic chemistry exam tomorrow, and I still could not wrap my head around methyl shift until I watched this video. You helped me solve an E1 reaction that I was completely lost on. Thank you so very much.
@Leah4sci
6 ай бұрын
Awww you're so welcome!
Leah you are super duper for chemistry.
@Leah4sci
Жыл бұрын
Thank you so much.
Enjoying organic . Thanks a lot .
@Leah4sci
3 жыл бұрын
You're welcome!
Great explanation ma'am. Thank u soo mch!!!
@Leah4sci
7 ай бұрын
Glad you liked it!
A very calm and clear explanation.
@Leah4sci
5 жыл бұрын
Thank you :)
Well I understood it so quick! Your brilliant, thank you!
@Leah4sci
6 ай бұрын
You're so very welcome!
Thank you!! An easy to understand video to help me study
@Leah4sci
3 жыл бұрын
You are welcome!
Best explanation ever ! Thank you !
@Leah4sci
5 жыл бұрын
Thank you! you're welcome :)
This is short and simple. thanks a lot!!!!
@Leah4sci
4 жыл бұрын
You're welcome!
Thank you so much ,great explanation
@Leah4sci
5 жыл бұрын
You're welcome! :)
Thank you so much for this video, it makes a lot of sense! Thanks!
@Leah4sci
6 ай бұрын
You're so very welcome, happy to clear it up!
@Thugbert0
6 ай бұрын
@@Leah4sci Hi Mrs. Leah! Crazy how time flies. I was talking to my wife about how much life has changed within the last decade. When I commented on that video, I has just left the USMC, met this girl (girl (Now wife! :) ), and thinking about a career in medicine. I am now a board certified FM physician with a small toddler. Thank you for your commitment to medicine and countless premeds around the world. GOD BLESS AND THANK YOU!
best chemistry video lesson ever watched. ..... I really thank you with all my conviction. P.S. :I am gunjan a science student in 12th and tomorrow is my first chem. exam of this new session.
@Leah4sci
7 жыл бұрын
You're welcome. Glad you liked it!
i feel very confident for my finals now thank u so much professor Leah
@Leah4sci
Жыл бұрын
You're welcome! I hope the finals went well. :)
@vee.333k
Жыл бұрын
@@Leah4sci got an A love youuu
You are great !! Really i am saying this for a reason.
@Leah4sci
6 жыл бұрын
Thank you for your kind words!
Awesome! Made alkyl shifts so much easier to understand
@imr4261
10 жыл бұрын
***** I finished my criminology major recently and realized I didn't want to become a cop or a lawyer lol so I chose to do my other major in biology so i could go into forensics. These videos are great for someone like me who is making the transition from social sciences to natural sciences. Thank you so much for your help! Orgo chem is a nightmare for all life science majors but these videos make it much easier :)
@imr4261
10 жыл бұрын
***** Oh, a whole bunch of stuff...chirality, prochirality, reaction mechanisms, bond disassociation energies...you name it. The most difficult parts so far are learning all of the different reagents and reactions involving alkenes/alkynes not to mention 'seeing' chiral molecules in 3d in your mind. These videos really help out a lot...I couldn't imagine how it would be 10 years ago and I'd have to go to the library just to read up on these topics. Thanks for taking the time and effort to post these videos. I know how thankless doing something like that can be, but if it's worth anything you really helped me achieve my goals (my exam is actually tmrw...wish me luck!).
@Leah4sci
6 ай бұрын
You're so very welcome, happy to help!
Amazing work. I like that the items are drawn/down so fast
@Leah4sci
6 ай бұрын
Glad you liked it!
Thank you so much. This cleared things up for me!
@Leah4sci
6 ай бұрын
You're so welcome, glad to clear it up!
Ma'am your videos r simply amazing , thank u so much .. :)
@hackerplanet1757
8 жыл бұрын
+Leah Fisch thanxx
@Leah4sci
6 ай бұрын
You're so welcome!
Loved ur explanation....best one!
@Leah4sci
6 жыл бұрын
Glad it helped!
you are a boss Leah!
@Leah4sci
6 ай бұрын
Thanks!
You make it so easy, thank you so much (:
@Leah4sci
7 ай бұрын
You're welcome, happy to help!
Outstanding! Thank you.
@Leah4sci
4 жыл бұрын
You're very welcome!
Can't believe I was a third grader when this came out and here I am watching this in the last year of my highschool 🤯
@Leah4sci
3 жыл бұрын
Classics never go out of style ;)
@keerthanasatheesh9639
3 жыл бұрын
@@Leah4sci KZread really do be a time machine
Thank you so much. Exam is Monday and I was struggling with rxns.
@Leah4sci
6 ай бұрын
You're so very welcome, happy to help!
How do you know when a reaction with a 1,2 C=C alkene will end up doing a hyride shift? Is it all of them or are there specific cases where a tertiary haloalkane is produced?
@Leah4sci
Жыл бұрын
It will perform a hydride shift, if doing so produces a more stable carbocation intermediate. Each situation is unique, and must be considered on an individual basis. For help with questions like this and more, I recommend joining the organic chemistry study hall. Details: leah4sci.com/join or contact me through my website leah4sci.com/contact/
Thank you ma'am☺️☺️
@Leah4sci
3 жыл бұрын
You're welcome!
Would a 1-Bromo-3-Methylpentane undergoing an E2 mechanism require any carbocation rearrangements? Also, can methyl and hydride shifts occur on all mechanisms? (SN1, SN2, E1 and E2)? Many thanks for your great videos!
@agent475816
8 жыл бұрын
+KoolViking3 Sn2 and E2 reactions do not create a carbocation. It is a one step process. The nucleophile attacks from behind and the leaving group leaves simultaneously.
So helpful! Thank you!
@Leah4sci
6 ай бұрын
You're so welcome, happy to help!
Thanks for the video, keep it up!
@Leah4sci
6 ай бұрын
You're so very welcome!
Leah4SciTutorials- u r awesome leah thank u so much love u really hepled me alot :)
@Leah4sci
6 ай бұрын
You're so very welcome!
Amazing! thank you very much
@Leah4sci
6 ай бұрын
You're so very welcome!
Omg you saved me!!!
@Leah4sci
3 жыл бұрын
Glad to hear it!
I LOVE YOU. Oh my god my brain was totally fried and I have a test tomorrow haha
@Leah4sci
6 ай бұрын
Aww thanks, happy to help!
Does this happen in free radical mechanism too? For example- monohalogenation of butane
@Leah4sci
11 ай бұрын
I'm sorry, but I don't offer tutoring over social media. If you ever find you need help with questions like this again, I recommend joining the organic chemistry study hall. Details: leah4sci.com/join or contact me through my website leah4sci.com/contact/
thxx u r a gerat teacher.......:)
@Leah4sci
6 ай бұрын
You're welcome!
You're so great! My professor talks way to fast and doesnt space out the steps for the mechanism. He prefers a short hand arrow push mechanism. And its very messy and hard to interpret. He could learn something from you!
@Leah4sci
4 жыл бұрын
Awww, thanks for your kind words! Glad I can help!
helped me a lot :) thank you!
@Leah4sci
6 ай бұрын
You're very welcome!
its really easy and awesome.
@Leah4sci
5 жыл бұрын
Great! Thanks for visiting. Don't forget to subscribe! :)
Very good 😊
@Leah4sci
Жыл бұрын
Thank you!
This is great but I'm wondering about the probability of shifting larger groups. Does this only work with hydrogen or methyl group or can you migrate any group? I'm just guessing that the bulkier groups won't go through this but I'm interested in the theoretical framework as to why.
@Leah4sci
6 жыл бұрын
These are great questions. I don't offer tutoring through KZread comments, but for more in-depth explanations on this and other orgo 1 & 2 topics, I recommend joining the orgo study hall. Full details: leah4sci.com/join
You explained this very well along with the simple yet appealing structures and shifts. The Female KhanAcademy!
@Leah4sci
6 ай бұрын
Happy to help!
Thank you :)
@Leah4sci
4 жыл бұрын
You're welcome!
would you look at that I didn't need to replay to actually get it. Thanks
@Leah4sci
3 жыл бұрын
Woohoo! You're very welcome :)
Thank you so much!!!
@Leah4sci
7 ай бұрын
You're welcome!
Does this reaction occur, I mean the shift of hydride if the compound was an alkyne ?
@Leah4sci
Жыл бұрын
Though I don't think it happens as often, any time we have a mechanism that proceeds through a carbocation intermediate, we have the possibility of rearrangement.
Leah you are a Chemistry Goddess
@Leah4sci
Жыл бұрын
Goddess? I don't know about that. Just an Organic tutor trying to help as many students as possible! :)
Wow thanks
@Leah4sci
2 жыл бұрын
You're welcome!
thanks leah. from south africa
@Leah4sci
6 ай бұрын
You're welcome!
realy good....
@Leah4sci
6 ай бұрын
Glad you liked it
Mam plz tell me that 1 4 or 1 5 hydride shift can occur or not
@Leah4sci
6 жыл бұрын
I'm sorry, but I don't offer tutoring through KZread comments. For help with this and more, I recommend joining the orgo study hall. Full details: leah4sci.com/join
thank u
@Leah4sci
5 жыл бұрын
you're welcome!
Lots of love from INDIA
@Leah4sci
6 жыл бұрын
Thanks!
At 4:20 how come is there H-OH2?
@sanjanamutyapu5513
5 жыл бұрын
H30+
@Leah4sci
4 ай бұрын
Instead of writing H3O+ I pulled out one H so that we can see the mechanism for grabbing it
4:49 you mean *bond pair of electrons* ?
@michaelpa1110
5 жыл бұрын
You’re right!
@Leah4sci
5 ай бұрын
oh wow, yes! 🤦 it's bonding electrons since a lone pair by definition has no bond
thanks
@Leah4sci
7 жыл бұрын
You're welcome!
thanx too much
@Leah4sci
6 ай бұрын
You're welcome!
Thankyou! :-) :-)
@Leah4sci
6 ай бұрын
You're so very welcome!
👍
@Leah4sci
3 жыл бұрын
:)
10 year old video + low quality graphics+quite slow voice +short duration= perfect
@Leah4sci
2 жыл бұрын
Glad you like it!
POV it is 2am and you have an orgo test tomorrow
@Leah4sci
3 жыл бұрын
How'd it turn out?
nice thanks I wish my professors would stop talking and just put on you tube during class. then at least attendance wouldn't be useless
@Leah4sci
6 ай бұрын
I'm happy I could help you and make it clear!
Anyone in yr 2022?
@Leah4sci
2 жыл бұрын
Me :)
Cool Voice ...... :P
@Leah4sci
6 ай бұрын
thanks!