Easy Way To Determine Ortho-Para or Meta Directing EAS WITHOUT Memorizing Anything!
Important points regarding EAS and Ortho-Meta-Para Directing substitutions on the benzene ring, and then an easy way to determine whether a substituent will be ortho-para or meta directing without having to memorize anything, especially when the examples on quizzes and tests may not even be on the table of ortho-meta-para directors!
For a better understanding, it may help to watch our video "Electron Withdrawing & Donating Groups: Polarity": • Electron Withdrawing &...
*Content Correct at 1:20: oops... I forgot to dash out the double bonds on the nitro group (NO2) [on the right-side molecule] to show resonance and alternating negative-charges on the oxygens rather than 5 bonds on the nitrogen
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Here's one more trick.....if the central atom of the attached group has a lone pair it is ortho para directing but if it has a pi bond then it is a meta directing 😅 hope it helps 😊
@PraxisAcademic
4 ай бұрын
Thank You so much for sharing this! This will of course be helpful!!
sis just saved my medical career , arguably the most educative video ive seen on organic chemistry
@PraxisAcademic
9 ай бұрын
Thank You so much! I am glad it helped! I truly appreciate your feedback!
This is the best explanation I have seen. My prof couldn't explain it in an hour but you did it so wonderfully in 6 minutes. Thank you so much!!
@PraxisAcademic
7 ай бұрын
Thank You so much for your much appreciated feedback! I am so glad this helped in a shorter amount of time!
I have my final exam this week for Organic Chemistry II, and this saved me . I usually need a reason why things happen in order to learn them correctly or for it to stick, and this clicked for me pretty fast! Certainly easier to remember than 15+ substituents.
@PraxisAcademic
6 ай бұрын
I am so glad this helped you for your final and you didn't have to memorize a ton of stuff! Thank You for watching. I hope finals went well for you!
This is perfect for me, exactly what i was lacking in abilities.
Wow sis, Thanks. You're really a life saver. I have been thinking for many weeks about this confused theory. NOW I GET THE THING. THANKS AGAIN.
@PraxisAcademic
Жыл бұрын
I'm glad it makes sense now! Thank You for watching!
Just the kind of explanation I needed to clear my concept. It's just wonderful how you made it so easy to understand. Thank you so much😊
@PraxisAcademic
5 ай бұрын
Thank You! I am so glad this made it more clear and easier to understand EAS! Thanks for watching!
I was unable to understand these things before watching this video... And you made it such a way... Wow i don't have words to express how i feel now!!! Thank you so much!!!❤
@PraxisAcademic
5 ай бұрын
I am glad this helped! Thanks for watching!
Thank you for your tutorials and making it easy to determine whether a substituent will be ortho-para or meta directing.
@PraxisAcademic
2 жыл бұрын
You're welcome! We aim to make orgo easier!
I will follow your advice from now on guys, you convinced me 😁😁
Thank you so much!! You saved me hours of excruciating and painful memorizing ❤️❤️❤️ This trick works so well each time I've used it 🔥🔥🔥
@PraxisAcademic
9 ай бұрын
I am so glad this ortho-meta-para trick works every time for you! It is something I figured out while helping DAT and MCAT students, recognizing that memorizing doesn't always help us remember things... haha..., and since it helped them every time, I thought I'd share it on KZread. Thanks for watching!
Thank you soo much ma’am. Your pace was wonderful, the explanations very clear and straight to the point. I really enjoyed the video ❤
@PraxisAcademic
9 ай бұрын
Thank You for your feedback! I am glad this helped you! And thank You for watching!
Wow, on point. Thank you so much on the tutorial on how to determine a compound is a deactivator or activator
@PraxisAcademic
10 ай бұрын
I am glad this helped! Thank You for watching!
this right here is high level explanation, never thought ochem could be that much fun thanks mrs
@PraxisAcademic
Ай бұрын
Thank You! I'm happy you see orgo as fun after this!
The best video… I really appreciate it🎉
A great way to improve yourself like this, awesome. 🥳
thank you so much for this video! you saved me so much time, i was worried i was gonna have to memorize things but this video was extremely helpful
@PraxisAcademic
8 ай бұрын
I am so glad this helped you! What's worse about trying to memorize all these molecules is that we can still have blank-out moments on tests. Thank You for watching!
Thanks for this wisdom
wonderful explanation
Thank you so much for this!!!!
@PraxisAcademic
Жыл бұрын
You're Welcome! Thank You for watching!
That could be a game-changer for me, I've always struggled with memorizing stuff.
@PraxisAcademic
2 жыл бұрын
I'm glad this helps with hard organic chemistry problems.
Thank you so much for making me to understand this
@PraxisAcademic
11 ай бұрын
I am glad this helped you understand EAS directing better!
never heard of that before, but glad I did now before it's too late :)
My professor never taught me this. I have my final exam tomorrow and I have tons of things to study, this made me way easier to learn this topic since I don't have so much time to memorise and remember so many things. Thank you so much!
@PraxisAcademic
5 ай бұрын
I am so glad this made it easier for EAS. I hope your final went well!
The NO2 has 5 connections to the nitrogen where it usually prefers 3 and one lone pair
@PraxisAcademic
3 ай бұрын
Thank You for pointing that out. I forgot to dash-out one bond on each of the O atoms to show resonance in the nitro, and there's not way of editing it now. I did include the correction in the description. Thank You for watching! And thanks for the feedback!
Fantastic explanation
@PraxisAcademic
5 ай бұрын
Thank You so much!
Spectacular explanation mam :) I love it and Thanks for your efforts
@PraxisAcademic
Ай бұрын
Thank You for watching!! I appreciate your feedback!
excellent! Thank you!
@PraxisAcademic
5 ай бұрын
Thanks for watching!
Tysmmmmmm you're the best !!
@PraxisAcademic
Жыл бұрын
I am glad this helped! Thank You for watching!
THANK YOU SO MUCHHHHHHH
Thank you so much for the explanation
@PraxisAcademic
Жыл бұрын
I am glad it helped! Thank You for watching!
Perfect explanation, thanks
@PraxisAcademic
2 жыл бұрын
I'm glad it was helpful! And thank you!
Wow this is a good mind-trick!
Thank you!
@PraxisAcademic
11 ай бұрын
You're welcome!
JEDI MIND TRICK RIGHT THERE! 💪
Brilliant!
@PraxisAcademic
Жыл бұрын
Thank You! I hope it helps in orgo!
helped me a lot for jee examination
@PraxisAcademic
4 ай бұрын
I'm so glad this helped on an exam! Thanks for watching!
Very good Explain
@PraxisAcademic
Ай бұрын
Thank You!
I love this 😊
@PraxisAcademic
Жыл бұрын
Thank You for watching!
I wish i could like this several times
@PraxisAcademic
Ай бұрын
Awww... that's so sweet of you! I appreciate you liking it!
Thank you so much ma'am. It will help me understanding organic chem very well. And yes, SUBSCRIBED for more from you ❤❤❤
@PraxisAcademic
Ай бұрын
I am glad this helped! And thank you for subscribing!
I wonder how I made it through school, wish I had know this sooner argh. 😋
Wonderful lecture as suits your channel name
@PraxisAcademic
4 ай бұрын
Thank You! I appreciate your feedback, and thank you for watching!
Waw excellent 👏
that's the perfect method, I owe you one guys Lol 😁
@PraxisAcademic
2 жыл бұрын
I am glad this helps!
thank you SO much... my exam is tomorrow 😅
@PraxisAcademic
Ай бұрын
Thank You for watching and using my trick. I hope the exam went well!
How can we then rank them to each other? Do we have to memorize it then?
@PraxisAcademic
Жыл бұрын
The more electronegative a substituent is, the more of an inductive effect it will have, meaning the more powerful it is as an electron-withdrawing group and the more likely it will be to determine where another substituent will substitute on to the benzene ring. So, rank them among each other based on electronegativity/inductive effect. For example, a -NO2 (nitro) has a greater electronegativity and inductive effect than a -COOH group, because even though both have two oxygens, nitrogen is more electronegative than carbon. For another example involving electron-donating groups, an -OH group versus a -NH2 group, the -OH group is more electronegative than the -NH2 group because oxygen is more electronegative and there’s only one H on the oxygen versus two on the nitrogen. Also, know that if there are already two substituents on a benzene ring-one more electronegative than the other OR one electron-withdrawing and the other electron-donating-substitute a third group meta to the more electronegative substituent OR meta to the electron-withdrawing group. For example, in the case of -OH versus -NH2 whereby -OH is more electronegative than -NH2, the -OH will have a greater electron-withdrawing inductive effect causing meta attachment from -OH of a third substituent. I hope this addresses your question and helps!
Great video. But I have a question, NH3 is considered deactivating and NH2 is considered activating. But why is that since the Nitrogen is more electronegative than the hydrogens?
@PraxisAcademic
9 ай бұрын
First--thank you! Second--excellent question! When an NH3 group is attached to the benzene ring, it will obtain a formal positive charge (N with 4 bonds is positive 1 charged) and is void of lone pairs (void of e-, essentially)); the positively charged N will then be super attractive to electrons, drawing electrons toward it, withdrawing electrons away from the ring (EWG, meta-directing, deactivating); in this case the positive charge on the N outweighs the effect of the electron donating groups attached to the N (this is even true for NR3+ groups). Formal charges are powerful! When an NH2 is attached to the ring, it'll only have 3 bonds keeping it at zero charge, maintaining its lone pair and usual electronegativity to pull electrons away from the Hs, become "electron-rich", and donate electrons to the ring.
@PraxisAcademic
9 ай бұрын
To help make this more clear, it helps to think about NH2 to NH- groups attached, both are electron-donating-groups and both are activating, but the NH- groups is a stronger activator because it has a -1 charge and is more electron rich, so it donates electrons to the ring.
@PraxisAcademic
9 ай бұрын
It's like the OH and O- groups; both are electron-donating-groups and activating.
@PraxisAcademic
9 ай бұрын
So, simply think of a group whereby if the alpha atom [to the ring] is negative, it will be electron-rich and donate to the ring. And a group whereby if the alpha atom [to the ring] is positive, it will be void of electrons and withdraw from the ring. Kind of like if you have no cash on you, you withdraw cash from the bank.
@PraxisAcademic
9 ай бұрын
I hope this helps further understand how to identify EDGs and EWGs!
maybe thats also good for seniors to keep their brain active!
@naahh
9 ай бұрын
hello???😭😭😭
I don't know none of that that's why am here
I am not good at memorizing anyway hahaha
cute voice
@PraxisAcademic
Жыл бұрын
Aw... thank you!
please do not make 5 bonds of nitrogen 💀
@PraxisAcademic
11 ай бұрын
Just seeing if anyone is paying attention... JK... I meant to dash those out to show resonance, but missed it in editing. 😬
oh my god thank you! i finally get it. i was so frustrated and disheartened trying to figure this out last night
@PraxisAcademic
Ай бұрын
I'm glad this helped!
Thank you!
@PraxisAcademic
Жыл бұрын
Thank You for watching!