IUPAC Nomenclature of Alkenes and Alkynes

More IUPAC nomenclature! Now let's look at molecules with carbon-carbon double and triple bonds. We will look at alkynes of alkenes. Get it?
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Пікірлер: 251

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  • @kevinkaria7057
    @kevinkaria70572 жыл бұрын

    4:43 Professor Dave I think that the higher priority would be given to a double bond rather than a triple bond while naming a compound with a double bond and a triple bond at the same position from either side. Please solve my ambiguity! Also your teaching style is awesome and far better than the IIT JEE tutions here in India!

  • @alitornado2

    @alitornado2

    2 жыл бұрын

    Yeah dude! The priority goes to the double bond first! Then comes triple bond and then single bond!

  • @CabbageSandwich

    @CabbageSandwich

    2 жыл бұрын

    @@alitornado2 The correct answer is both. This video is slightly dated on its naming conventions. With some new IUPAC conventions since this video came out 7 years ago, we treat the en and yne suffixs the same way he treats the alcohol suffix in this video, except stacked in the same name, ill show you below. Additionally because of this change, we don't use "#-(carbons)(ene)" anymore. e.g "3-ethene" If we want to specify the position of a double bond in ethene, we input a space into the name, for instance, "2-chloro eth-1-ene". This also allows us to use stereochemistry modifiers E and Z to signify cis and trans double or triple bonds like this, "3-chloro pent-1(Z)-yne", a 5 carbon chain with a chlorine on the third carbon, and that has a bent first carbon on a triple bond at the number 1 carbon. To answer your question though. An actual name of a six carbon chain with a double and triple bond on the ends is "hex-1(E/Z)-en-6(E/Z)-yne". Where the E/Z considers the stereochemistry of the bond *e.g whether the first/last carbon is on the same side or opposite side from carbon #3 / #4 respectively. You can consult some various sources for this on the new Blue Book rules but I used this one. www.masterorganicchemistry.com/2011/02/14/table-of-functional-group-priorities-for-nomenclature/

  • @nayachi341

    @nayachi341

    Жыл бұрын

    @@CabbageSandwich hello, i have a query regarding the same, if a triple bond is closer than the double bond, then from which way the numbering should start?

  • @CabbageSandwich

    @CabbageSandwich

    Жыл бұрын

    IUPAC convention is that naming would start from the end closer to the triple bond. depending on exactly what you mean here.

  • @gbadebosamson8423

    @gbadebosamson8423

    10 күн бұрын

    I think double bound should be given higher priority .I just watch a video where it was given

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    @curtpiazza16882 жыл бұрын

    Wow....you make it look so easy! Great stuff!

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  • @legusurting
    @legusurting7 ай бұрын

    Thank you, Professor Dave, thanks to you I can learn Alkynes of useful stuff.

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  • @junkilee0301
    @junkilee03012 жыл бұрын

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  • @Sleepiful
    @Sleepiful Жыл бұрын

    Enjoying the videos so far. I was confused what happens if the double or triple bond is not on the longest chain. As far as I understand from a quick search, it's the longest chain containing the double or triple bond which is used for numbering.

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    @Motosfourlife5 жыл бұрын

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    @bubzbubbly128 жыл бұрын

    Hey Professor Dave, can you make a video on IUPAC of ethers? Your videos are extremely helpful. Thank you so much!!!

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    @kalpadil20188 жыл бұрын

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    @tracyscanlon45877 жыл бұрын

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  • @helmetongrass1893
    @helmetongrass189311 ай бұрын

    just remember guys that the priority order for lowest occurance and in the selection of the principal carbon chain is Functional group (like OH, COOH, etc...) > unsaturated bond (double and triple bond)> Longest carbon chain (number of carbon atoms) > substituent groups (like F, Cl, Br, I, methyl, ethyl, etc...)

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    I don't enjoy chemistry, but he just makes it so interesting.

  • @eelboy9017
    @eelboy90177 жыл бұрын

    Thank you again profs , have to submit answers to 100+ questions on IUPAC naming tommorow =w=

  • @momedsy
    @momedsy10 ай бұрын

    très bonne explication merci beaucoup

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    @englishwithshehryar97308 жыл бұрын

    it was so helpful

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    @donnam47304 жыл бұрын

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    @Gt500rh7 жыл бұрын

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    @athiramohan69124 жыл бұрын

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    @parulaggarwal94055 жыл бұрын

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    @user-cw3js9pj5h2 жыл бұрын

    Thanks

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    @yasmeenmallick26666 жыл бұрын

    Thnxx sir.. For ur explanation

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    @Lucky_W_S2 жыл бұрын

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  • @shush9013
    @shush9013 Жыл бұрын

    cheers

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    @PeaceboneGotFound3 жыл бұрын

    Thank you!

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    @YamenLahham-xm2cl

    Ай бұрын

    hi

  • @sachinkumar9868
    @sachinkumar98688 жыл бұрын

    Prof Dave can u make a clip on backbonding.....

  • @SovietProxy
    @SovietProxyАй бұрын

    Exam tomorrow thank you

  • @jxlryj
    @jxlryj3 жыл бұрын

    Thank you! Amen.

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    @catarinafernandes89842 жыл бұрын

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    @liwayasutana25193 жыл бұрын

    If I only knew this video exists, I wouldn't have headache back then :D

  • @rassimsimou1594
    @rassimsimou15942 жыл бұрын

    Good

  • @aubreymacasinag1340
    @aubreymacasinag13403 жыл бұрын

    Sir is it still necessary that you will put 1 before pentene?

  • @nkonajoelafor4016
    @nkonajoelafor40163 жыл бұрын

    You are best prof please sir I wish to ask if it's hept-3-yne or 3-heptene I love you sir God bless you

  • @dieselguitar1440
    @dieselguitar14403 жыл бұрын

    Other sources are saying that alkenes and alkynes have the same priority but priority is given to alkenes for alphabetization in the event of a tie. I may have misread them.

  • @akashsunil7464
    @akashsunil74643 жыл бұрын

    professor Dave what if there an alkene and an alkyne together in the compound what do we do ??????

  • @kjk464
    @kjk4647 ай бұрын

    I have a question: If that was an alkyne instead of an alkene at the end, would the suffix be "butyn-1-ol"? instead of "butyne-1-ol"?

  • @davidkeyes3540
    @davidkeyes3540 Жыл бұрын

    I also wanted to ask-- why are we not including Z/E stereoisomerism in this IUPAC name?

  • @kayecatipay4033
    @kayecatipay40334 жыл бұрын

    Thank uuu!!!

  • @Knolittle-04
    @Knolittle-045 ай бұрын

    Regarding to that 1 on pente-1-nol in your next video of cyclic compounds you said it is implied that the hydroxyl group is on carbon1 thereby not writing the 1 on the final answer but here you wrote it there may i get to understand why?is it because that one was a cyclic and this one isn't....am confused now about numbering compounds with functional groups 😭

  • @priyanshu--010
    @priyanshu--0102 жыл бұрын

    Professaur....DAVE

  • @vindyakelum90
    @vindyakelum9011 ай бұрын

    Awesome ❤❤❤❤

  • @harshihash1569
    @harshihash15694 жыл бұрын

    Ur osm in ur ownkind in doin orgo simpler than our professors who made it complex Plz cover the topics like preparation of hydrocarbons I wish u would do it bruhh...◉‿◉

  • @ninjanahja8421
    @ninjanahja84212 жыл бұрын

    Love your work man! But our professor told us Alkynes have the lowest priority..

  • @bonfacechwara8172
    @bonfacechwara81728 жыл бұрын

    Prof explain on eclipse and staggered conformation

  • @ProfessorDaveExplains

    @ProfessorDaveExplains

    8 жыл бұрын

    +bonface chwara check out my clip on conformational analysis of ethane and butane!

  • @emmanuel284
    @emmanuel2842 жыл бұрын

    Chemistry Dave grohl just saved me

  • @harishsasankarm9428
    @harishsasankarm94283 жыл бұрын

    Why did you use the dash and hash (whatever it is) in place of actual methyl line representing the Methyls in the first formula of Alkenes?

  • @ProfessorDaveExplains

    @ProfessorDaveExplains

    3 жыл бұрын

    check out the first tutorial in this organic chemistry playlist, it explains the dash and wedge notation

  • @SixthOption
    @SixthOption3 жыл бұрын

    thanks professor dave :3 my gf never listens to me but she WILL listen to YOU

  • @marvinne30412
    @marvinne304122 ай бұрын

    Is it still okay if the suffix is hept-3-en-1-ol?

  • @sweetzcv9373
    @sweetzcv93733 жыл бұрын

    Hello sir! Love your teachings always, it is much easier and clearer than my profs at school who makes it more difficult to understand. Anyways i do have one question to clarify. Aren''t alcohols termed as OH? 😶

  • @ProfessorDaveExplains

    @ProfessorDaveExplains

    3 жыл бұрын

    an OH is a hydroxyl group, and a molecule with a hydroxyl group is called an alcohol

  • @sweetzcv9373

    @sweetzcv9373

    3 жыл бұрын

    @@ProfessorDaveExplains okk, thank you sir for the reply😊

  • @nejaahalcyon
    @nejaahalcyon3 жыл бұрын

    I would have a question : in the example at 4:10 what makes us choose the top path? Is there a rule about chosing a path that minimize the number of bonds in the substituants? With the same example taking the lower path would mean that the group would be 3 bonds long while taking the top one makes a 2 bond group. Am I extrapolating this correctly? Or maybe there is a rule that state that family modifiers must be attached to the main chain, forcing to choose the path with the hydroxyl group. In case the bottom path is valid what would be the name of this thing?

  • @ProfessorDaveExplains

    @ProfessorDaveExplains

    3 жыл бұрын

    The parent chain must contain the hydroxyl group, it's the highest priority group.

  • @nejaahalcyon

    @nejaahalcyon

    3 жыл бұрын

    @@ProfessorDaveExplains Thank you for clearing this up for me, and thank you for these incredibly well made videos.

  • @swwarnock
    @swwarnock3 жыл бұрын

    Prof Dave, @6:22, because of the double bond, would we be expected to write this as cis-5-chloro-3-ethyl-4-methyl-hepten-1-ol? or is there a reason we don't need to identify the cis/trans conformation?

  • @ProfessorDaveExplains

    @ProfessorDaveExplains

    3 жыл бұрын

    so this would require E/Z nomenclature, i just haven't covered yet at this point in the series, there's another tutorial on that

  • @ceciliaalicona1704
    @ceciliaalicona17045 жыл бұрын

    I had a problem on a test that I didn't understand when naming. The compound is 4-chloro-1-methyl-2-propylcyclohexane. Why does the count in counting the carbon chain starts with the methyl and not the chlorine? I thought since Chlorine not being a carbon chain would take priority in naming, then I would counts backwards making the propyl third and the methyl fourth. Could you explain why the priority. Thanks. Love watching your videos.

  • @ProfessorDaveExplains

    @ProfessorDaveExplains

    5 жыл бұрын

    so for cyclic compounds its totally different, check out my tutorial on IUPAC for cyclic compounds!

  • @deenabandhu2482
    @deenabandhu24823 жыл бұрын

    what if a compund contains both double bond and triple bond?

  • @davidkeyes3540
    @davidkeyes3540 Жыл бұрын

    Can I write 4,4-dimehtyl pent-1-ene, or does it have to be 4,4-dimehtyl-1-pentene? I also did 6-iodo hexan-3-ol instead of 6-iodo-3-hexanol. Is that correct? Please only comment if you are an expert in this. Thanks!

  • @ProfessorDaveExplains

    @ProfessorDaveExplains

    Жыл бұрын

    interchangeable

  • @yashovardhandubey5252
    @yashovardhandubey52524 жыл бұрын

    At 6: 23 prof Dave is flicking his luscious hair

  • @karunyakumar1552
    @karunyakumar15522 жыл бұрын

    Nice intro song 😀

  • @mytech6779
    @mytech67793 жыл бұрын

    Now this has two longest carbon chains so why isn't this 5-chloro-4-methyl-3-hepten-3-ethanol?(Or 5-chloro-3-ethaanol-4-methyl-3heptene)?

  • @0oYCRo0
    @0oYCRo06 жыл бұрын

    Hi Prof. Dave. I wanted to ask, can we start by numbering the chain from the carbon that's below the alcohol (The one you called 3-ethyl), instead of the one that's right next to it?

  • @ProfessorDaveExplains

    @ProfessorDaveExplains

    6 жыл бұрын

    nope! longest carbon chain must contain the hydroxyl group.

  • @stan9095

    @stan9095

    5 жыл бұрын

    Glad someone already asked this question. So in that case location of the hydroxyl constinutent indicates the main carbon chain? Sweet

  • @asdfzxcv4176

    @asdfzxcv4176

    Жыл бұрын

    hey man thanks for asking it

  • @victorzoma2749
    @victorzoma27493 жыл бұрын

    Why hydroxyl given highest priority? 😊logic behind please!

  • @steffaniesainato5322
    @steffaniesainato53226 жыл бұрын

    Quick question. In the Alkene example you labled the substituent double bond 1-1-pentene. How come on this one it is not 3-3-3-heptyne, and it's just 3-heptyne?

  • @ProfessorDaveExplains

    @ProfessorDaveExplains

    6 жыл бұрын

    that's an L for the end of methyl! it's just 1-pentene. we need just one number to indicate the location of the pi bond(s).

  • @steffaniesainato5322

    @steffaniesainato5322

    6 жыл бұрын

    Awesome! Ok thank you. I was confused for a second. Can I just say I am loving your Ochem videos. I haven't taken this course yet but am prepping for my MCAT so in addition to my Kaplan test prep materials I am using this as a supplement. It is way easier to understand from you, and honestly it seems like Ochem is going to be fun. Never thought I would ever say that lol.

  • @yasyasmarangoz3577
    @yasyasmarangoz35773 жыл бұрын

    4:28 why the upper one? Why not the one under it?