Gilman Reagent & Organocuprates
This organic chemistry video tutorial provides a basic introduction into the Gilman reagent also known as an organocuprate. It discusses how to synthesize the organocuprate from an organolithium reagent. It also discusses the reaction between alkyl halides and unsaturated ketones with the gilman reagent.
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Thanks for the example at the end, that was really helpful for understanding the point of Gilman
Thank you once again.
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Bro this is underrated video, its an AIEEE 2005 question :)
Last question was helpful
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Is this topic (the gilman reagent) a very popular question on the PCAT?
thank you
Thanks
Haha Gilman reagent the same week we mention them First exam next Tuesday 👌🏾
Hello does anyone know if it is possible to use (cyclopentyl)culi ?
Underrated
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@ashokchoudhary4709
3 жыл бұрын
I am also from india for which are you preparining
@nevermind4329
3 жыл бұрын
@@ashokchoudhary4709 I know you came here after solving ms chouhan Grignard reagent chapter
@kjiitr
2 жыл бұрын
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@basicallyapotato5410
Жыл бұрын
@@ashokchoudhary4709 jee advanced 2024
How is it that Gilman reagents can replace halides on sp2 hybrodized carbons (seeing as that can't happen w/ the SN2 mechanism). Is this mech not SN2?
@WiShInGdRaGoN1324
3 жыл бұрын
Gilman reagents can undergo both addition and nucleophilic reactions. In the case of alpha, beta unsaturated ketones, it's (conjugate) addition. For alkyl halides, it's a carbon-carbon-making SN2 reaction
please make more biology videos thanks
But sir grignard also do 1-4 addition
Sick!! But wheres the mechanism dawg? Is this a metal mediated thing? Association? Reductive elimination?? Whats going on my dude?
isnt a big part of gilman reagents that they can replace the Cl of a acid chloride
@WiShInGdRaGoN1324
3 жыл бұрын
Yes, into a ketone, and it reacts no further.
What’s a veno or aero halide
show the curly arrows please