Carbon-13 NMR Spectroscopy

This organic chemistry video tutorial provides a basic introduction into carbon-13 NMR spectroscopy. It covers broadband decoupled C-NMR where all signals appear as singlets as well as proton-coupled C-13 NMR spectroscopy where the signals appear as doublets, triplets, and quartets based on the N+1 rule splitting pattern of the hydrogen atoms that are directly attached to the carbon atoms. It also discusses DEPT C-13 NMR spectroscopy which is useful for identify C, CH, CH2, and CH3 carbons. This video explains how to assign the chemical shifts to different carbons given the C-13 NMR spectrum as well as proposing a structure given the molecule and using factors such as IHD and the number of signals present in the spectrum. Finally, this video discusses the different chemical shifts of functional groups such as alkyl groups like methyl, methylene, and methine groups as well as halogens, amines, alkenes, alkynes, ethers, alcohols, benzene rings, aldehydes, ketones, esters, and carboxylic acids.
Alcohol Reactions - HBr, PBr3, & SOCl2:
• Alcohol Reactions - HB...
Free Radical Reactions:
• Free Radical Reactions
Reactions Summary:
• Organic Chemistry Reac...
Organic Chemistry 1 Final Exam Review:
• Organic Chemistry 1 Fi...
IR Spectroscopy:
• IR Spectroscopy - Basi...
Mass Spectrometry:
• Mass Spectrometry
______________________________
Proton NMR Spectroscopy:
• Proton NMR Spectroscop...
Ethers and Epoxides:
• Ether and Epoxide Reac...
Diels Alder Reaction:
• Diels Alder Reaction
Organic Chemistry 2 Final Exam Review:
• Organic Chemistry 2 Fi...

Пікірлер: 174

  • @TheOrganicChemistryTutor
    @TheOrganicChemistryTutor5 ай бұрын

    Organic Chemistry PDF Worksheets: www.video-tutor.net/orgo-chem.html Full-Length Exams and Worksheets: www.patreon.com/MathScienceTutor/collections

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    @josephrossman16005 жыл бұрын

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    @idk-jw2jn

    5 жыл бұрын

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    @hadeerrashad54862 жыл бұрын

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  • @camweekley7413
    @camweekley7413 Жыл бұрын

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  • @hosman1391
    @hosman13914 жыл бұрын

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    @absolutebagel50285 жыл бұрын

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    @captainoaoaoa6908

    3 жыл бұрын

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    3 жыл бұрын

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    @Exhalted1

    3 жыл бұрын

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    2 жыл бұрын

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    @asilsakka3173

    2 жыл бұрын

    @@sparky844 professor dave explains

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  • @alinamoreno9235
    @alinamoreno92353 жыл бұрын

    i STRUGGLED with this in ochem 1 and within an hour you've helped me understand it in ochem 2!! thank you!!!!

  • @sveasmith8139
    @sveasmith81393 жыл бұрын

    You're a legend. Thankyou for being the reason im passing this class!

  • @kranthikumarpudota8535
    @kranthikumarpudota85353 жыл бұрын

    hi your explanation is amazingly easy to understand and the enormous amount of examples u furnish to understand the concept with a detailed mechanistic approach is invaluable

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    @marilynnaeem61365 жыл бұрын

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  • @samuelwamwere4867
    @samuelwamwere4867 Жыл бұрын

    I took me just 1 night to go through each example you've used above to understand a 7 lesson Graduate NMR Class! May God bless you!

  • @michellecampa9850
    @michellecampa98503 жыл бұрын

    im starting to undertand this after a week lmao thank you. I was feeling so lost and i cant even make a meeting with my professor cause i have severe social anxieaty :( so you literally just saved me

  • @Aaron_Orion
    @Aaron_Orion4 жыл бұрын

    Christ, this was so obvious I feel dumb! Killin' myself to figure out NMR and how to properly analyse the spectra, but I feel confident now, hopefully the exam will go fine! You've definitely helped me, you're a great tutor. Keep up the good work!

  • @songohan393
    @songohan3932 жыл бұрын

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    @hayqahassan172 жыл бұрын

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  • @wisehead1830
    @wisehead18302 жыл бұрын

    Thank you so much, I went through all the spectroscopy videos and I think I get it now.

  • @lisatryemka9775
    @lisatryemka97753 жыл бұрын

    Thank you so much for this video. The topics are explained in such a concise and clear way. Watching your videos has helped me appreciate the beauty of chemistry, I'm planning on rocking a JG hoodie when I ace my Orgo class!

  • @abhi523
    @abhi5232 жыл бұрын

    Respected Sir You explained everything so systematically..... Wonderful job.... Thank you so much. 🙏🙏🙏

  • @jackspratt9316
    @jackspratt93163 жыл бұрын

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    @roomiemcgee88993 жыл бұрын

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  • @etoileViral
    @etoileViralАй бұрын

    Wow, this video is incredibly informative and detailed. The explanation of carbon-13 NMR spectroscopy is clear and concise, covering everything from the basics of broadband decoupled C-NMR to DEPT C-13 NMR spectroscopy. The examples provided, such as 2-butanol and 2-methylbutane, really help to illustrate how to assign chemical shifts to different carbons given the C-13 NMR spectrum. I especially appreciated the discussion on how to propose a structure given the molecule and using factors such as IHD and the number of signals present in the spectrum. The video also does a great job of explaining the different chemical shifts of functional groups, including alkyl groups, halogens, amines, alkenes, alkynes, ethers, alcohols, benzene rings, aldehydes, ketones, esters, and carboxylic acids. The score system for ranking the chemical shifts of sp3 carbon atoms is also very useful. Overall, this video is a must-watch for anyone studying organic chemistry

  • @josephk3306
    @josephk33063 жыл бұрын

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  • @betafilms969
    @betafilms9694 жыл бұрын

    Thank you for providing comedic relief by choosing to place a peak at 69 when you could have easily moved it.

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    @chemworldjaveria59194 жыл бұрын

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    @simonpeapo95212 жыл бұрын

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    @workpual4251 Жыл бұрын

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    @bernardkwakuosei57013 жыл бұрын

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    @masoudrafee20464 жыл бұрын

    Many thanks for your edifying lectures on chemistry

  • @danielgladish2502
    @danielgladish25024 жыл бұрын

    Very helpful and made the concepts very clear and easy to understand. I would like to note, however, that the integration (peak height) of the C13 peaks is the result of the number of protons on the carbon not the number of equivalent carbons.

  • @keeda8500
    @keeda85003 жыл бұрын

    Seriously, I attented a whole semester of lectures about nmr spectroscopy (held by a physicist, considered the best of his field) and I did not understand a single thing. After watching this video I am pretty sure I will get through the exam.

  • @likeangng3219
    @likeangng32194 жыл бұрын

    Thanks for the clear explanation!! It helps alot!!

  • @user-zr2mc7zz3l
    @user-zr2mc7zz3l2 жыл бұрын

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  • @khalidmohammadu7895
    @khalidmohammadu78954 жыл бұрын

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    @aliyakhan70974 жыл бұрын

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    @suhaibkhrayyef65202 жыл бұрын

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    @goldenfishes36954 жыл бұрын

    This is so very thorough

  • @sabamunawar202
    @sabamunawar2022 жыл бұрын

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  • @TheStabbinCabin
    @TheStabbinCabin5 жыл бұрын

    All your videos are fantastic, thanks for your help. Can you make a review video for the ACS Organic Chemistry I and II exam?

  • @desirjayy
    @desirjayy5 жыл бұрын

    You’ve helped me a great deal in General Chem 1/2 and Organic Chem 1/2. I was wondering if you can cover Med. Chem? I’m going to Pharmacy School soon thanks too you. So i know i’ll need some help lol.

  • @Annie-it1cw

    @Annie-it1cw

    4 жыл бұрын

    I'm a Pharm.D student and I'm using his videos!

  • @wisehead1830

    @wisehead1830

    2 жыл бұрын

    This so funny to me cause you should learn Med.Chem at Pharmacy School but instead you have to come here for some real help. All the best in Pharmacy School

  • @fatimahalquraysh6580
    @fatimahalquraysh65803 жыл бұрын

    It is more than helpful. Thank you

  • @soaringred8929
    @soaringred8929 Жыл бұрын

    This taught me more about 13C NMR than 4 years of high school chemistry and 1.5 years of a biochem degree ever have

  • @lanomadaventurera
    @lanomadaventurera5 жыл бұрын

    OMGGGGG!! Are you taking Orgo 2 now, anyways thank you sooo muchh! I love you...respect for you

  • @anniemshine4477
    @anniemshine44775 ай бұрын

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  • @philipsine7674
    @philipsine76743 жыл бұрын

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    @naimulislam33095 ай бұрын

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    @catarinamacedo28643 жыл бұрын

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  • @ssstudentt
    @ssstudentt8 ай бұрын

    You are #1 in NMR, bro!

  • @marasmithson6218
    @marasmithson62184 жыл бұрын

    Hey I just had to write a comment since you kind of saved my ass in quarantine with ALL of your spectroscopy videos I watched after having a breakdown over my so called "MSc.-Level-scipts"... Thank you so so so much.

  • @nathanielukah5058

    @nathanielukah5058

    3 жыл бұрын

    Where can i get more of such videos please?

  • @karthikkd3471

    @karthikkd3471

    3 жыл бұрын

    @@nathanielukah5058 www.khanacademy.org/science/organic-chemistry/spectroscopy-jay

  • @user-wq2bp1zc4c
    @user-wq2bp1zc4c4 жыл бұрын

    Thx dude, that helps a lot

  • @ProfNajib
    @ProfNajib2 жыл бұрын

    crystal clear, thank you dude

  • @saminanoor8094
    @saminanoor8094 Жыл бұрын

    It was an amazing lecture...thank u so much for this 😊

  • @asmakhan9442
    @asmakhan94424 жыл бұрын

    Great job...thank you.

  • @Meradulie
    @Meradulie3 жыл бұрын

    you saved me. Had to understand nmr in 2 days to not fail my laboratory module...

  • @BOBLIKESCHEESEYT
    @BOBLIKESCHEESEYT Жыл бұрын

    This guy is a legend

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    @omadullohburkhonov7109 Жыл бұрын

    you are a true legend.

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    @saki79525 жыл бұрын

    May be this will help me in the future.

  • @sarbeshojha4747
    @sarbeshojha4747 Жыл бұрын

    Really very informative.

  • @studybuddy3462
    @studybuddy34625 жыл бұрын

    It's very good video 👍

  • @almirasulejmani5312
    @almirasulejmani5312Ай бұрын

    you really helped me,thank youu🥰🥰❤️

  • @devjyotinath1084
    @devjyotinath10844 жыл бұрын

    Very helpful video! Thank you so much. I have a question. Do we get another peak If the adjacent nitrogen protonates for a certain percentage of the molecule (e.g. 10mol% of CH3-CH2-CH2-CH2-NH2 is protonated and form CH3-CH2-CH2-CH2-NH3+; do we see two separate peaks for the adjacent C of the N for these two molecules).

  • @oshadhaprabhashwara69
    @oshadhaprabhashwara699 ай бұрын

    Thank you, all the way from the University of Peradeniya in Sri Lanka

  • @fashionconsultantofficial2097
    @fashionconsultantofficial2097 Жыл бұрын

    You are amazing.it help me alot

  • @ees5640
    @ees5640 Жыл бұрын

    We need teachers like him in our universities 🙏💕 those PhD holder professors can't teach like this , and only insult students by saying that , you guyz are not hardworking , you guyz are not paying attention , you guyz are just passing your time in university, you have no interest in studies ..bla bla bla 😑 but the reason they can't teach properly , they even make simple things so much difficult with their extraordinary explanation that either we get confused or we just give up by thinking that we are not intelligent .. and when we ask questions they start scolding Infront of everyone and make fun of us ...😤 We are not duffer students , we need right teachers who teach us without make us feel dumb !!!❤️🌟✨

  • @suzanucan1868
    @suzanucan1868 Жыл бұрын

    Hi there. I am a pharmacy student at İnönü University in Turkey. I have a Pharmaceutical Chemistry Lab quiz tomorrow and I'll be able to do something about it thanks to you.

  • @ayobamiolatunji6878
    @ayobamiolatunji68785 жыл бұрын

    You may have saved my grades :-)

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    @nishanthawijesinghe65302 жыл бұрын

    CIE exam in 3 days with chem 1st , thank you saved me😌🙏

  • @rubafahmiabbas4294
    @rubafahmiabbas42942 жыл бұрын

    Iam from iraq . I appreciate your explain ..thank you so much

  • @mariamt8011
    @mariamt80113 жыл бұрын

    Thank you ! ❤❤❤❤

  • @ansammkh1681
    @ansammkh16812 жыл бұрын

    thank you very much

  • @gordanchew2453
    @gordanchew24535 жыл бұрын

    So how do you explain why at 10:48min why does a secondary carbon has a higher chemical shift than tertiary carbon if they both have a score of 4?

  • @scottwatson6901

    @scottwatson6901

    5 жыл бұрын

    Well i'm about 5 months late but maybe this will help someone else... The carbon that has the score of 4 but is neighboring a tertiary carbon will end up having a higher "score". The other carbon with a score of 4 has a neighboring secondary carbon giving it a lower score than the other one. think of the neighboring carbon(s) as a tie breaker in these situations.

  • @LunaMatrix

    @LunaMatrix

    4 жыл бұрын

    @@scottwatson6901 " but maybe this will help someone else" I was that someone, thank you king!

  • @mmpcy710
    @mmpcy7105 жыл бұрын

    are you can do a videos about IR & UV spectroscopy please please 😭

  • @bennettegaper4344
    @bennettegaper43443 ай бұрын

    Thank you so much

  • @juanfranciscofeliu3544
    @juanfranciscofeliu35445 жыл бұрын

    Dude, my spectroscopy teacher’s salary should go to your wallet, thank you!

  • @tadiwanashegwiza

    @tadiwanashegwiza

    8 ай бұрын

    😂😂😂😂

  • @nermeinkhalid1570
    @nermeinkhalid15702 жыл бұрын

    u r ausome thank u😭💙

  • @charlottezepeda8566
    @charlottezepeda85662 ай бұрын

    very helpful

  • @matteomoioli5210
    @matteomoioli52104 жыл бұрын

    First of all, thank you for the perfect explanation, simple and clean. But i want to make a question: why does ketones have more cs than , for example, carboxylic acid? I mean : does not the electronegativity of Oxygen "take off" the electrons from the Carbon atom, reducing his screen for the external magnetic field, causing an increase of chemical shift ? I do not understand that. Thank you an keep it up !

  • @floopirossi3745

    @floopirossi3745

    2 жыл бұрын

    Bc carboxylic acids have resonance

  • @26d8
    @26d83 жыл бұрын

    For example, #6, wasn't the carbon b a tertiary carbon with a score value of 3 due to 3 primaries around?

  • @assialaib1642

    @assialaib1642

    2 жыл бұрын

    i am wondering the same

  • @rizwanurrahmanabeer1429
    @rizwanurrahmanabeer14293 жыл бұрын

    Thank you!!! :)

  • @dr.josephnhyiraobessey6908
    @dr.josephnhyiraobessey69084 жыл бұрын

    Any help please...what's the number of carbons does cyclohezone has on 13 cnmr

  • @chirathdesilva3822
    @chirathdesilva38224 жыл бұрын

    Can someone explain the 13C of 2,2,4trimethyl-1,3pentandiol.cuz this system wont work for that.and there are similar ch3 groups having different peaks.

  • @michaelosei7901
    @michaelosei79015 жыл бұрын

    thank you

  • @abhishekroy9921
    @abhishekroy99212 жыл бұрын

    EXCELLENT

  • @weightelk
    @weightelk4 жыл бұрын

    Thank you

  • @christopherallbright3749
    @christopherallbright37493 жыл бұрын

    @TheOrganicChemistryTutor At 29:25 Isnt carbon A a tertiary carbon, making the score of carbon B 4 which would give the higher chemical shift anyways?

  • @sydneynguyen4987
    @sydneynguyen49873 жыл бұрын

    Better than my prof ngl

  • @user-ey3yn6vu8o
    @user-ey3yn6vu8o9 ай бұрын

    The reason I love Ochem

  • @thomasmuller8558
    @thomasmuller8558 Жыл бұрын

    Man U R amazing

  • @tanmoydutta5039
    @tanmoydutta50392 жыл бұрын

    Why does 13C have such a wider range as compared to 1H NMR?

  • @DzmitryMukha1
    @DzmitryMukha15 жыл бұрын

    25:00 Why do you call the second carbon in 2-chlorobutane as tertiary, while later naming the first carbon in 1-chlorobutane as primary?

  • @mtrav1

    @mtrav1

    5 жыл бұрын

    as far as I can tell, he is wrong.

  • @muslim19800

    @muslim19800

    3 жыл бұрын

    I know too late for you, may be other needs this; it is secondary caron not tertiary... the role is how many carbon atom attached to that carbon, if only one it is primary, if 2 carbon the secondary and so on .... nitrogen has the same principle, how many carbons attached to that nitrogen atom... sorry for the delay

  • @stephpham3507
    @stephpham35074 жыл бұрын

    im confused. how come around 1:22:00 when he talks about H NMR he's not using the adjacent carbon's hydrogens to determine the split pattern?

  • @samanthasonntag6463

    @samanthasonntag6463

    4 жыл бұрын

    Because the example wasn't HNMR. He was saying if it was then you would look at the adjacent hydrogen atoms. This is a transcript from my textbook about 13C NMR: "First, no splitting is observed between neighboring carbon atoms because of the low abundance of 13C. The likelihood of a compound having two neighboring 13C atoms is quite small, so 13C-13C splitting is not observed. In contrast, 13C-1H splitting does occur, and it creates significant problems. The signal of each 13C atom nucleus is split not only by the protons directly connected to it (separated by only one sigma bond) but also by the protons that are two or three sigma bonds removed. This leads to very complex splitting patterns, and signals overlap to produce an unreadable spectrum. To solve the problem, all 13C-1H splitting is suppressed with a technique called broadband decoupling, which uses two rf transmitters. The first transmitter provides brief pulses in the range of frequencies that cause 13C nuclei to resonate, while the second transmitter continuously irradiates the sample with the range of frequencies that cause all 1H nuclei to resonate. This second rf source effectively decouples the 1H nuclei from the 13C nuclei, causing all of the 13C signals to collapse to singlets. The advantage of broadband decoupling comes at the expense of useful information that would otherwise be obtained from spin-spin coupling. A technique called off-resonance decoupling allows us to retrieve some of this information. With this technique, only the one-bond couplings are observed, so CH3 groups appear as quartets, CH2 groups appear as triplets, CH groups appear as doublets, and quaternary carbon atoms appear as singlets. Nonetheless, off-resonance decoupling is rarely used because it often produces overlapping peaks that are difficult to interpret. "

  • @aratimaurya8464
    @aratimaurya84645 жыл бұрын

    why alkyne have low 13C valu than alkene??

  • @maggiem9291
    @maggiem92912 жыл бұрын

    saved my life

  • @lh9591
    @lh95915 жыл бұрын

    Can you do some problems that combine IR, H NMR, and C NMR? e.g. formula C5H8Cl2 what is the structure? IR (cm-1): 2950 1H NMR (δ): 1.4 (4H, triplet), 1.2 (4H, triplet) 13C NMR (ppm): 62 (singlet), 26 (triplet), 23 (triplet) i want to cry :( :(

  • @OfficialNekoPk
    @OfficialNekoPk Жыл бұрын

    Sir can you make video on 2 d nmr spectroscopy and please explain tocsy cosy hmbc hsqc spectra ? I will really appreciate it.

  • @Pardeep-PN2427
    @Pardeep-PN24274 жыл бұрын

    Thanks

  • @himanshusinghal8100
    @himanshusinghal81004 жыл бұрын

    Sir , i have a humble request to u ,can u explain pavia book chapter 6 problem no. -15 plzz sir

  • @yili9857
    @yili98574 жыл бұрын

    very useful : ) one confusion: when you talking about the triple bond group example, I think the carbon with triple bond should be 3° not secondary carbon. Please check~ I learn all chemical analysis stuff by your video.

  • @raanoooshh9296

    @raanoooshh9296

    4 жыл бұрын

    A carbon with a triple bond cannot be bound to three R-groups and cannot therefore be a tertiary carbon, since a carbon atom cannot form five bonds.

  • @jennablue5763

    @jennablue5763

    4 жыл бұрын

    I was wondering the same thing! Cb should have a score of 5 and Cc a score of 7.

  • @SsSss-hq3xp
    @SsSss-hq3xp4 жыл бұрын

    On voit tjrs un pic à 78 dans RMN c13 cela signifie quoi ? Et des fois se cache ??

  • @anchalrathore2151
    @anchalrathore21515 жыл бұрын

    Thank you sooo much and please provide us COSY NOSY lecture... please