If its got "sigma" in it then you know it goes hard
@b3dubbs72Сағат бұрын
NurdRage would love this
@ZoonCrypticon4 сағат бұрын
Except for the ugly picture of "you know who" a great and colorful video nice to watch.
@bobsmith60799 сағат бұрын
Another perfect video! Try adding the dragon spit to liquid ozone and liquid fluorine just for fun.
@perlundqvist761212 сағат бұрын
Inject that into the veins😮
@mandardeodhar40013 сағат бұрын
You are so amazing. Thank you very much
@chloehennessey681316 сағат бұрын
Well that’s it. I’ve seen it all now. A tomato had Taco Bell. 9:05
@theotopakis912019 сағат бұрын
Hi! Since there is tert-Butyllithium, is there also tert-Butylrubidium or tert-Butylcesium; and will they be much more reactive than tert-Butyllithium?
@mattmiller461319 сағат бұрын
Thats actually weapons grade!
@msfit2321 сағат бұрын
Watching this vid with an overcoat and sunglasses with the collar flipped up so NileRed doesn't see me cheating....
@ACME_Kinetics23 сағат бұрын
I worked at UPS. They could absolutely find a way to destroy that packaging.
@alch3myau23 сағат бұрын
argh. Gotta start video again, Wasnt watching in 4k
@klori111Күн бұрын
I would like to see you put a drinking glass full of this stuff inside a safe😂
@picobyteКүн бұрын
The flame turning green may be the coppercontainer burning.
@ManicPandazКүн бұрын
I keep on thinking “you really should go to a doctor if it looks like this when you go to the washroom.”
@tracybowling1156Күн бұрын
I love how the sulfur looks like lightning! It's beautiful.
@417iszazaheavenКүн бұрын
I done this on my stove.
@Fireworxs2012Күн бұрын
*In case it was lost on you, watching all the cool explosions. The REAL message of this Video is...* *Never piss off a Chemist*
@manso306Күн бұрын
what's the heaviest smoke?
@fano72Күн бұрын
Burning sulfur is magic. Edit: Your video recordings are magical.
@stormchaser-necosun1329Күн бұрын
Love that Voldemort editing!
@floppy8568Күн бұрын
you should write a paper on it or something
@floppy8568Күн бұрын
Don't actually call it ChemicalForce reaction of course, call it the Felix reaction or something like that
@mehmetmuslimov559Күн бұрын
Very likely that titanium tetrahydride doesn't exist at all
@ChemicalForceКүн бұрын
mb, I've seen a lot of conflicting information about TiH4
@NebulonRangerКүн бұрын
t-BuLi is the stuff of nightmares. The day when we can use something that isn't an extremely reactive alkali metal bonded to an extremely reactive alkane group in its place on a general level will be a momentous one lol
@Angrychemist666Күн бұрын
Ok! Was a little let down when it touched off the LOX! I was expecting something Wiley Coyote, but only got Chinese firecrackers! 😢😢😢
@ChemicalForceКүн бұрын
I expected the same as you :D
@floppy8568Күн бұрын
5:42 I don't know for sure, but maybe it's carbon and boron??? I have no idea, just a guess.
@Angrychemist666Күн бұрын
He has a good lineup with Mr. Felix's laboratory! I recently synthesized tertbutyllithium and that was one of those experiments that youre only 12 minutes into and thinking OH SHIT! Why do I bite off way more than I can chew! 😂 but it was ment for me to proceed as my childhood friend and lab partner from University just happened to get back early from Germany ! And was Umm!!! Yeah sorta happy to assist me, but he had that OMG WTF did you get into this one for look on his face😮! BECAUSE ITS TERTBUTYLLITHIUM! AND ITS MY FAVORITE SUPER BASE!🔥🔥🔥🧪⚗🧫🧯🧯🧯🔬
@djisydneyaustraliaКүн бұрын
8:15 more impressive in ozone I think.
@djisydneyaustraliaКүн бұрын
Highly oxygenated boron ? Lithium would burn easier and give the red flame where additional oxygen would break the lithium boron bond and allow it to burn I assume ?
@yarharyarКүн бұрын
Fuck I love this channel... MORE EXOTIC FIRE!
@djisydneyaustraliaКүн бұрын
Highly oxygenated boron ? Lithium would burn easier and give the red flame where additional oxygen would break the lithium boron bond and allow it to burn I assume ?
@djisydneyaustraliaКүн бұрын
2:20 very reminiscent of plasma , the upper layer of flame at least
@CalilasseiaКүн бұрын
A thought occurs to me ... since using hydrazine results in exothermic reactions with numerous selenium reagents, and black selenium results, could you obtain red selenium by reacting the compounds in a refrigerated microfluidic device? Cool it it dry ice and ensure that only milligram quantities of reagent react at any one time.
@ChemicalForceКүн бұрын
To obtain red selenium you can simply use a more dilute hydrazine solution :D
@weedmanwestvancouverbc9266Күн бұрын
Some non-metallic elements have such strange chemistry.. I'm curious how many of them have allotropes like sulfur oxygen and phosphorus do
@CalilasseiaКүн бұрын
That is one excellent collection of camera shots! Your next mission, should you choose to accept it ... replicate this with trimethylaluminium or one of the dialkyl zincs. For those unfamiliar with these particular pyrophoric flamethrowers, they make tert-butyllithium look tame. Straight dimethylzinc is an accident waiting to happen except in the hands of a VERY skilled chemist, and even then, a LOT of precautions need to be taken. If that reagent cuts loose in an uncontrolled fashion, mayhem on an industrial scale ensues. But, the compounds I've just mentioned produce some interesting flame colours of their own, and would probably be spectacular to watch in liquid oxygen. Provided this can be done without lethal shrapnel and flaming debris of course, which is ALWAYS a hazard to be aware of with this pair of organometallics. A less explosive, but dangerously toxic one, is dimethylcadmium. Though that again is a choice for bunker chemistry. Far rarer are actinide organometallics, though I suspect no one outside a national security institution will ever be able to perform even simple experiments with those. I'm also wondering what would happen with organometallic caesium compounds. Which again probably comes under the heading of bunker chemistry. Or, for that matter, various methyl derivatives of various transition metals. Though generating hexavalent chromium in any quantity is, er, not advisable for the unskilled. Though of course, even this collection of nightmare experiments pales into insignificance once dioxygen difluoride or chlorine trifluoride are part of your collection of reagents. Oddly enough, Derek Lowe has several interesting accounts of vicious organometallics, along with FOOF and ClF3 on his chemistry blog. Delivered in his own inimitable style. Recommended reading for those who want to see hideously dangerous chemistry sprinkled with fun metaphors.
@ChemicalForceКүн бұрын
I've already filmed studio material with trimethylaluminum and now I’m waiting for the opportunity to conduct experiments with it. ibb.co/jrZw8By But first just open this can without burning the laboratory and the entire building :D
@NinjalordsaltКүн бұрын
i love the part where the fruits shit themselves
@ChemicalForceКүн бұрын
On April 1st I released a separate video where I give alkali metal injections to various fruits :D
@PaulSteMarieКүн бұрын
The color change with the borohydride: is it possible that adding the liquid oxygen resulted in further oxidation of the combustion product? The temperature difference could also be a factor, but usually higher temperatures result in shorter wavelength spectral lines becoming dominant.
@gerolifiumКүн бұрын
1:50 forbidden piss 💀💀💀
@RocknR00sterКүн бұрын
Destin, from SmarterEveryDay would love that shot @10:53!
@harish-rn6obКүн бұрын
Danger lies in Beauty well defined
@KargonethКүн бұрын
Beautiful fireworks. Thanks for the upload.
@KargonethКүн бұрын
A conical reaction vessel could be interesting as deflected blobs would be guided back to the center.
@ChemicalForceКүн бұрын
no, the walls of the vessel will quickly become covered with ice, and then the vessel with smoke :D
@timothybaca6527Күн бұрын
FIRE FIRE FIRE!!!!
@KargonethКүн бұрын
The lithium borohydride showed the green of boron once oxygen was added. Perhaps the red of the lithium oxidizing is less bright than the boron oxidizing, so we see the green, preferentially. A spectroscopic analysis through the reaction would be able to confirm whether both colours arw present and the ratio of their relative brightness.
@davidbarts6144Күн бұрын
I would guess boron is involved in the green color of burning lithium borohydride. Perhaps unless LOX is added to the mix, not enough boron is volatilized to color the flame.
@konstantinkhlopenkov4492Күн бұрын
You produce such impressive contents with beautiful flames, but can you upload an HDR version? KZread should support HDR, and the flames do need a high dynamic range, which you can enjoy with your eyes, but not us viewing it through the screen...
@ChemicalForceКүн бұрын
Unfortunately my camera only records 8 bit 4:2:0. My high speed camera can do this, but its buffer is only five seconds. I hope that in the near future I'll be able to update my camera and I'll manage to record 4:2:2 10 bit, then I'll be able to add HDR video. Thank you very much for the donation!
@supernovahm1178Күн бұрын
When we were 11, maybe 12 - studying the reactions of the alkali metals in science class, we were all desperate to see what potassium would do (since we were allowed to react sodium in person and it was crazy). We could find one or two super low-resolution video and microblocked-to-hell videos of it. People with access to this channel and in general, the insane number of videos on KZread are just so lucky.
@daviddrewniak8966Күн бұрын
2:39 Part of my current PhD research is investigating the combustion aspects of a couple borohydrides, including LiBH4. It's currently not well understood exactly what is happening when LiBH4 burns (thus the research), but here is my theory. It is well known from the literature that LiBH4 decomposes to LiH, B, and H2 at low heating rates. Upon further heating, LiH decomposes and free Li atoms are released. Lithium has a low boiling point and a high vapor pressure, so many Li atoms make their way into the flame zone and react, giving us that beautiful red flame. Boron has a very high boiling point and low vapor pressure, making it difficult to burn in a diffusion flame, even without an oxide layer that is present on most boron particles (the boron oxide layer is why boron is notoriously difficult to burn quickly and efficiently). The flame from LiBH4 powder burning in air is a diffusion flame that is heating the powder relatively slowly, thus why we see only the Li burning and not the B. How LiBH4 reacts under rapid heating is not well understood. There is a theory (DOI:10.1021/cm100536a) that B2H6 is formed when LiBH4 decomposes. When heating rate is slow, the diborane then reacts with additional molten LiBH4 to form a Li2B12H12 intermediate species, which eventually decomposes further to LiH, B, and H2. However, under rapid heating, like when pure liquid oxygen is poured on the burning powder, the B2H6 does not have time to react with the molten LiBH4 and instead escapes the melt as a gas where it burns to HBO2 and B2O3, with the intermediate species BO2 giving off the green color! Side note on the colors: the red color from the Li is one wavelength; 671nm. So it is "pure" red. The green from BO2 comes from resonance lines in the 500-580nm range, so it's actually a mix of blue-green, green, and yellow-green. The strongest resonance line is at 546nm, which is the apple green that we see.
@swirlingabyssКүн бұрын
I was way off. I was thinking of some kind of self quenching.
@mhtrproplayerКүн бұрын
that's exactly true I think
@nigeldepledge379012 сағат бұрын
Does not the hydrogen also contribute to the red colour?
@davidwhatever904110 сағат бұрын
i left chemistry after my phd, this reminds me how much i miss it
@daviddrewniak8966Сағат бұрын
@@nigeldepledge3790 Hydrogen flames are nearly invisible, giving only a very faint blue color due to the presence of OH radicals. A great example of this is the Space Shuttle Main Engine, which used liquid hydrogen and oxygen as propellants. A slight blue tint to the flame is noticeable, but the nozzle exhaust is transparent enough to see right up into the engine as it is running.
@Dewey_the_25UКүн бұрын
For those who are colour blind, the colours he states are accurate!
@brendanguymer3885Күн бұрын
You shouldn’t even remove t-BuLi from the bottle without another trained chemist assisting
Пікірлер
If its got "sigma" in it then you know it goes hard
NurdRage would love this
Except for the ugly picture of "you know who" a great and colorful video nice to watch.
Another perfect video! Try adding the dragon spit to liquid ozone and liquid fluorine just for fun.
Inject that into the veins😮
You are so amazing. Thank you very much
Well that’s it. I’ve seen it all now. A tomato had Taco Bell. 9:05
Hi! Since there is tert-Butyllithium, is there also tert-Butylrubidium or tert-Butylcesium; and will they be much more reactive than tert-Butyllithium?
Thats actually weapons grade!
Watching this vid with an overcoat and sunglasses with the collar flipped up so NileRed doesn't see me cheating....
I worked at UPS. They could absolutely find a way to destroy that packaging.
argh. Gotta start video again, Wasnt watching in 4k
I would like to see you put a drinking glass full of this stuff inside a safe😂
The flame turning green may be the coppercontainer burning.
I keep on thinking “you really should go to a doctor if it looks like this when you go to the washroom.”
I love how the sulfur looks like lightning! It's beautiful.
I done this on my stove.
*In case it was lost on you, watching all the cool explosions. The REAL message of this Video is...* *Never piss off a Chemist*
what's the heaviest smoke?
Burning sulfur is magic. Edit: Your video recordings are magical.
Love that Voldemort editing!
you should write a paper on it or something
Don't actually call it ChemicalForce reaction of course, call it the Felix reaction or something like that
Very likely that titanium tetrahydride doesn't exist at all
mb, I've seen a lot of conflicting information about TiH4
t-BuLi is the stuff of nightmares. The day when we can use something that isn't an extremely reactive alkali metal bonded to an extremely reactive alkane group in its place on a general level will be a momentous one lol
Ok! Was a little let down when it touched off the LOX! I was expecting something Wiley Coyote, but only got Chinese firecrackers! 😢😢😢
I expected the same as you :D
5:42 I don't know for sure, but maybe it's carbon and boron??? I have no idea, just a guess.
He has a good lineup with Mr. Felix's laboratory! I recently synthesized tertbutyllithium and that was one of those experiments that youre only 12 minutes into and thinking OH SHIT! Why do I bite off way more than I can chew! 😂 but it was ment for me to proceed as my childhood friend and lab partner from University just happened to get back early from Germany ! And was Umm!!! Yeah sorta happy to assist me, but he had that OMG WTF did you get into this one for look on his face😮! BECAUSE ITS TERTBUTYLLITHIUM! AND ITS MY FAVORITE SUPER BASE!🔥🔥🔥🧪⚗🧫🧯🧯🧯🔬
8:15 more impressive in ozone I think.
Highly oxygenated boron ? Lithium would burn easier and give the red flame where additional oxygen would break the lithium boron bond and allow it to burn I assume ?
Fuck I love this channel... MORE EXOTIC FIRE!
Highly oxygenated boron ? Lithium would burn easier and give the red flame where additional oxygen would break the lithium boron bond and allow it to burn I assume ?
2:20 very reminiscent of plasma , the upper layer of flame at least
A thought occurs to me ... since using hydrazine results in exothermic reactions with numerous selenium reagents, and black selenium results, could you obtain red selenium by reacting the compounds in a refrigerated microfluidic device? Cool it it dry ice and ensure that only milligram quantities of reagent react at any one time.
To obtain red selenium you can simply use a more dilute hydrazine solution :D
Some non-metallic elements have such strange chemistry.. I'm curious how many of them have allotropes like sulfur oxygen and phosphorus do
That is one excellent collection of camera shots! Your next mission, should you choose to accept it ... replicate this with trimethylaluminium or one of the dialkyl zincs. For those unfamiliar with these particular pyrophoric flamethrowers, they make tert-butyllithium look tame. Straight dimethylzinc is an accident waiting to happen except in the hands of a VERY skilled chemist, and even then, a LOT of precautions need to be taken. If that reagent cuts loose in an uncontrolled fashion, mayhem on an industrial scale ensues. But, the compounds I've just mentioned produce some interesting flame colours of their own, and would probably be spectacular to watch in liquid oxygen. Provided this can be done without lethal shrapnel and flaming debris of course, which is ALWAYS a hazard to be aware of with this pair of organometallics. A less explosive, but dangerously toxic one, is dimethylcadmium. Though that again is a choice for bunker chemistry. Far rarer are actinide organometallics, though I suspect no one outside a national security institution will ever be able to perform even simple experiments with those. I'm also wondering what would happen with organometallic caesium compounds. Which again probably comes under the heading of bunker chemistry. Or, for that matter, various methyl derivatives of various transition metals. Though generating hexavalent chromium in any quantity is, er, not advisable for the unskilled. Though of course, even this collection of nightmare experiments pales into insignificance once dioxygen difluoride or chlorine trifluoride are part of your collection of reagents. Oddly enough, Derek Lowe has several interesting accounts of vicious organometallics, along with FOOF and ClF3 on his chemistry blog. Delivered in his own inimitable style. Recommended reading for those who want to see hideously dangerous chemistry sprinkled with fun metaphors.
I've already filmed studio material with trimethylaluminum and now I’m waiting for the opportunity to conduct experiments with it. ibb.co/jrZw8By But first just open this can without burning the laboratory and the entire building :D
i love the part where the fruits shit themselves
On April 1st I released a separate video where I give alkali metal injections to various fruits :D
The color change with the borohydride: is it possible that adding the liquid oxygen resulted in further oxidation of the combustion product? The temperature difference could also be a factor, but usually higher temperatures result in shorter wavelength spectral lines becoming dominant.
1:50 forbidden piss 💀💀💀
Destin, from SmarterEveryDay would love that shot @10:53!
Danger lies in Beauty well defined
Beautiful fireworks. Thanks for the upload.
A conical reaction vessel could be interesting as deflected blobs would be guided back to the center.
no, the walls of the vessel will quickly become covered with ice, and then the vessel with smoke :D
FIRE FIRE FIRE!!!!
The lithium borohydride showed the green of boron once oxygen was added. Perhaps the red of the lithium oxidizing is less bright than the boron oxidizing, so we see the green, preferentially. A spectroscopic analysis through the reaction would be able to confirm whether both colours arw present and the ratio of their relative brightness.
I would guess boron is involved in the green color of burning lithium borohydride. Perhaps unless LOX is added to the mix, not enough boron is volatilized to color the flame.
You produce such impressive contents with beautiful flames, but can you upload an HDR version? KZread should support HDR, and the flames do need a high dynamic range, which you can enjoy with your eyes, but not us viewing it through the screen...
Unfortunately my camera only records 8 bit 4:2:0. My high speed camera can do this, but its buffer is only five seconds. I hope that in the near future I'll be able to update my camera and I'll manage to record 4:2:2 10 bit, then I'll be able to add HDR video. Thank you very much for the donation!
When we were 11, maybe 12 - studying the reactions of the alkali metals in science class, we were all desperate to see what potassium would do (since we were allowed to react sodium in person and it was crazy). We could find one or two super low-resolution video and microblocked-to-hell videos of it. People with access to this channel and in general, the insane number of videos on KZread are just so lucky.
2:39 Part of my current PhD research is investigating the combustion aspects of a couple borohydrides, including LiBH4. It's currently not well understood exactly what is happening when LiBH4 burns (thus the research), but here is my theory. It is well known from the literature that LiBH4 decomposes to LiH, B, and H2 at low heating rates. Upon further heating, LiH decomposes and free Li atoms are released. Lithium has a low boiling point and a high vapor pressure, so many Li atoms make their way into the flame zone and react, giving us that beautiful red flame. Boron has a very high boiling point and low vapor pressure, making it difficult to burn in a diffusion flame, even without an oxide layer that is present on most boron particles (the boron oxide layer is why boron is notoriously difficult to burn quickly and efficiently). The flame from LiBH4 powder burning in air is a diffusion flame that is heating the powder relatively slowly, thus why we see only the Li burning and not the B. How LiBH4 reacts under rapid heating is not well understood. There is a theory (DOI:10.1021/cm100536a) that B2H6 is formed when LiBH4 decomposes. When heating rate is slow, the diborane then reacts with additional molten LiBH4 to form a Li2B12H12 intermediate species, which eventually decomposes further to LiH, B, and H2. However, under rapid heating, like when pure liquid oxygen is poured on the burning powder, the B2H6 does not have time to react with the molten LiBH4 and instead escapes the melt as a gas where it burns to HBO2 and B2O3, with the intermediate species BO2 giving off the green color! Side note on the colors: the red color from the Li is one wavelength; 671nm. So it is "pure" red. The green from BO2 comes from resonance lines in the 500-580nm range, so it's actually a mix of blue-green, green, and yellow-green. The strongest resonance line is at 546nm, which is the apple green that we see.
I was way off. I was thinking of some kind of self quenching.
that's exactly true I think
Does not the hydrogen also contribute to the red colour?
i left chemistry after my phd, this reminds me how much i miss it
@@nigeldepledge3790 Hydrogen flames are nearly invisible, giving only a very faint blue color due to the presence of OH radicals. A great example of this is the Space Shuttle Main Engine, which used liquid hydrogen and oxygen as propellants. A slight blue tint to the flame is noticeable, but the nozzle exhaust is transparent enough to see right up into the engine as it is running.
For those who are colour blind, the colours he states are accurate!
You shouldn’t even remove t-BuLi from the bottle without another trained chemist assisting