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Terry Hope - Casting Thin, Tough Bioplastics Casein

The book you need that talks all about Casein plastics is available from www.fwgltd.co.uk - it's on the download page. You don't need to use formaldehyde but the plastic won't be as tough nor will it be waterproof

Пікірлер: 59

  • @josephknightcom
    @josephknightcom9 жыл бұрын

    And thank you for the link to the cool turn-of-the-century book on casein. Wow. To think, how many lifetimes of experience went into that single compilation. And how it is practically lost to general common knowledge of the tinkering public. Thanks for opening casein back up as an alternative to toxic, smelly petroleum materials.

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    I am going to be doing more on this - it is a fascinating subject

  • @josephknightcom
    @josephknightcom9 жыл бұрын

    You sir are a scholar of ... those things you do. Thumbs up.

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    cheers mate

  • @TerryHope
    @TerryHope4 жыл бұрын

    Wow Thnx Robert.. Never seen this until today !!

  • @TheMNBlackBear
    @TheMNBlackBear Жыл бұрын

    I've got to make this thicker! For use in making guitar picks!

  • @kefex
    @kefex3 жыл бұрын

    So the ammonia (or other alkali) doesn't prevent the casein from setting? Is that because it evaporates as well? If one used sodium bicarbonate, would it leave a residue?

  • @mandolinman2006
    @mandolinman20062 жыл бұрын

    I have a question as someone who isn't a chemist without much access to chemicals. I'm looking to make some galalith that's somewhat clear in a tortoiseshell pattern for guitar picks. How would I pull this off?

  • @BorutPeterlinPhotography
    @BorutPeterlinPhotography9 жыл бұрын

    I'm working with carbon printing process (I think your brother does that too) and this tip is very very very useful. I will experiment along your lines. By the way, today I've published a video on my channel how I'm doing my carbon prints. With the help of your videos I'm inspired to see carbon print process as something that is not a word of god, but something it could be pimped up, make it better... Your videos are very inspiring, thank you.

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    your are right he does and platinum printing - i will fascinated to see what you come up with - i have just started to experiment with ammonium ferric citrate and gelatin

  • @BorutPeterlinPhotography

    @BorutPeterlinPhotography

    9 жыл бұрын

    In either case you'll get a print from me. Ebay auctions are saying they are becoming a currency for me! Thx mate!

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    Borut Peterlin bless your heart mate - looked through your channel by the way - nice work! - clearly a labour of love

  • @BorutPeterlinPhotography

    @BorutPeterlinPhotography

    9 жыл бұрын

    ... or as my wife would call it: behaviour disorder! THX ;-)

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    Borut Peterlin lol no worries mate

  • @joubertpoglia2627
    @joubertpoglia26273 жыл бұрын

    my friend could you go through the recipe step by step how can i make galalite?

  • @junseonglee8078
    @junseonglee80784 жыл бұрын

    Hello, We are the students who are from South Korea and writing paper about Casein plastic. However there are problem that we don't know what is casein plastic's molecular formula and decomposing process. Can you tell me Casein plastics's molecular formula and decomposing process?

  • @zaneaussie
    @zaneaussie4 жыл бұрын

    Hey Rob, I am looking to make a thin (PEM) membrane material as the heart of my experimental fuel cell and will be adding Mica as the proton carrier. I assume you can just add glycerin or sulphur to make it slightly rubbery but my question is around how you where able to cast it so thin and so accurately?

  • @ThinkingandTinkering

    @ThinkingandTinkering

    4 жыл бұрын

    there is a linear relationship between percentage of solid against percentage of carriers - if you cast a 100 micron film with 35% solids it will dry to 35 microns - you can use that to manipulate film thickness

  • @anonymoussesm
    @anonymoussesm9 жыл бұрын

    Thank you so much for the video. I bought the book and was looking for how many parts alkali to add to the casein in order to dissolve it. Does the solution just turn clear when its fully dissolved? I wanted to add sodium bicarbonate instead as an alkali and was just wondering if that would not work as well as ammonia. Also, could a similar process be used with whey protein?

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    kind of a clear very slightly amber and carbonates work well too - though sodium carbonate - washing soda - would be better. Whey protein is going to be slightly different - it's going to take you a while to get to grips with casein so if i were you i would concentrate on that - get it up and running then turn your attention to other materials - that's just a suggestion though

  • @gonzlocarrera9949
    @gonzlocarrera99494 жыл бұрын

    Hello sir!, Im very interested in bioplastics, already have been trying with starch and cross linking it with citric acid to try to get a waterproof cloth. (just wanted to see if I could avoid using casein).I tried using tea and it didn't work lol. Big amounts of citric acid seems to be the best so far. I wonder if soy protein could replace milk??? And cross link it with tannic acid or tea??? Also, I would like to buy your casein bioplastics book, but the link seems to be broken. Thank you again for your channel!!! Have a good day!

  • @zebedie2
    @zebedie29 жыл бұрын

    Do you know if there's a way to use Casein in the context of 3d Printers?, since it's a thermoset instead of a themoplastic I think it can't be re-melted once it's set and most printers work via a spindle of prior extruded material. If there was a way to optically cure it once a layer of it was put down that might be one way, or keep it in a state where it was thick enough to "print" without setting prior to printing that might be another way

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    I don't think you will be able to get it to do that mate - solvent casting might be a way forward but still a challenge - it can be optically cured but optical curing involves some pretty harsh photo initiators and cross linkers

  • @bhavinivaghela166
    @bhavinivaghela1664 жыл бұрын

    Sir i want to add copper nano into my bioplastic into my project but i am confused how to go ...i m phd student plz suggest me

  • @DeliciousDeBlair
    @DeliciousDeBlair7 жыл бұрын

    Have you tried adding anything like over the counter water suspended acrylic like a concrete sealer to experiment with various properties? I am hoping before long to also experiment with refining and playing around with pine tree rosins with those items like toll oil, although at this point I know nothing about them chemically, I grew up playing with it as it makes a very interesting ultra thin film when reacting with water directly from a fresh young candela* [a word I grew up with and which I can not find on an internet search so I do not know if it is a proper term] when dropped in water. The reaction is rather exuberant and will propel the piece of pine across the water like a little motor although it often twirls and seldom goes straight, and most of the propulsion is from water tension and drag than from anything you would cal real thrust and it leaves a super fine film which can some times be carefully lifted out, although it breaks easily, and it can float a pin on occasion, if you can lay the pin on it carefully enough. I know that amber is the product of resins but not if its anything useful for creating working plastics. Any types of other natural materials one can add would be interesting. If I have any success, I will be sure and post the results where it can be found on my account.

  • @ThinkingandTinkering

    @ThinkingandTinkering

    7 жыл бұрын

    go for it

  • @mihalamm
    @mihalamm9 жыл бұрын

    Dear Sir, Is this casein plastic heat resistive? Could someone use it to create high voltage electrodes from it e.g. with and without graphene as additive?

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    it's a protein based plastic - so no - well no more than most

  • @sebastianguzmanolmos263
    @sebastianguzmanolmos2635 жыл бұрын

    Hi Robert, first of all, thanks so much for the data, love your video! I truly do. I've been watching your casein ones so many times for a design university project, I'm trying to make an MDF-ish type of material using casein as a binding substance. I have two main question, what's the difference of using borax or alkali in the mixture and the second one is if there's an effective formaldehyde replacement (commercially available). I can't find a clear answer in google scholar. Thanks again!

  • @stauffap

    @stauffap

    4 жыл бұрын

    I just experimented a bit with Casein glue. I used CaOH and Calcium Caseinate. The mixture gels up and does not dissolve in water. When i put it in tannic acid there was a very clear reaction with the tannic acid (it stained the gelled up glue and i wasn't able to wash it off). So my guess is that there's some cross linking going on. Maybe this will harden your material. I made some leather before and what happend when i put the dried casein glue into tannic acid felt a lot like what happened when i vegetable tanned leather.

  • @alessiahale4849
    @alessiahale48498 жыл бұрын

    Are there any alternatives to formaldehyde? I would want to use it, but I'm doing a science fair project and formaldehyde is banned.

  • @ThinkingandTinkering

    @ThinkingandTinkering

    8 жыл бұрын

    yes there are alternatives - do some research - try google scholar

  • @thagrit
    @thagrit9 жыл бұрын

    What name would we be looking for to purchase casein as a casting material? All I found looking on eBay was a health food additive and it was fairly expensive. Love your vids Robert keep it up.

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    sodium caseinate - you are either going to have to buy an unflavoured health food which is casein or stump up for a 25 kg sack of the stuff

  • @aldiwiranata8112
    @aldiwiranata81124 жыл бұрын

    how do cast it, because in experiments I always fail

  • @joeglory425
    @joeglory4259 жыл бұрын

    I'm curious to know what the resistance through the thickness of the graphite plastic sheet is ? I may find it useful for the "dry stack" battery concept I'm working on.

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    i'm at home now - i'll measure it tomorrow

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    250 ohms per square at 10 microns thick - which makes it 100 ohms per square per mil - but i made no effort to maximise conductivity - i just put 50:50 binder to ink in a jar and mixed it up for the demo

  • @joeglory425

    @joeglory425

    9 жыл бұрын

    Robert Murray-Smith It's conductive and that's pretty good! I've mixed graphite with melted PE. I didn't get a nice pretty sheet and it wasn't conductive. In my application I'd be using the conductivity from the top of the sheet to the bottom of the sheet rather than along the plane of the sheet.

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    Joseph Richardson might well be the way to go - if you are using an acid electrolyte you probably wouldn't need the formaldehyde step as casein is insoluble in weak acid

  • @wumbodude2750
    @wumbodude27507 жыл бұрын

    hi can you make a mold tuturiol thank you or can you buy one and where thanks very much

  • @replanet2114
    @replanet21148 жыл бұрын

    How exactly do you cast it with the mold? I'm confused. Can you make your own mold? With what?

  • @ThinkingandTinkering

    @ThinkingandTinkering

    8 жыл бұрын

    of course make your own and with whatever will make a mold - there are a mllion ways to make a mold

  • @Donatellangelo
    @Donatellangelo8 жыл бұрын

    Oh, it's explained here more. Thanks! ;D

  • @ThinkingandTinkering

    @ThinkingandTinkering

    8 жыл бұрын

    +Donatellangelo no worries

  • @abdallahafifi4552
    @abdallahafifi45527 жыл бұрын

    Greetings Robert. I would like to, first, thank you for sharing your knowledge and experience with us. I, sincerely, thank you for that. Second, after the mold is cured in formaldehyde and dried, could the mold, itself, become carcinogenic?

  • @ThinkingandTinkering

    @ThinkingandTinkering

    7 жыл бұрын

    I don't know I suppose you would have to test it

  • @leonardjanus7599
    @leonardjanus75999 жыл бұрын

    Urine Electrolyte Supercapacitor pubs.rsc.org/en/content/articlelanding/2014/tb/c4tb00739e#!divAbstract They use pectin but I imagine that also casein can be uses... if don't dissolve with urine.

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    or urea

  • @6969smurfy
    @6969smurfy9 жыл бұрын

    Corn Starch is what I use, really any starch will work. . just to keep it Bio. I never tried formaldehyde? This would make it a non Bio film correct? I been thinking of trying to carbon fiber some of these materials? Drawl them down as far as possible, to align the links, then 3 step heat treatments to see if this is something that can be done at home. I imagine a carbon fiber made out of natural ingredients instead of The Poly Acrylics would have some interest. Nice information for me these last couple of Videos. Rock on Robert! Peace Out Murf!

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    lol - no worries mate - but adding formaldehyde wouldn't ruin the bio usp - bio refers to the source of monomer - anyway formaldehyde is naturally occurring in apples etc and is completely biodegradable - if you don't like the name formaldehyde your allowed to call it methelyne glycol if it is in water and normally it is - it's a protein cross linker so no good for starches which are polysaccharides.

  • @user-py9cy1sy9u

    @user-py9cy1sy9u

    9 жыл бұрын

    This reminded me of petition that called dihydrogen monoxide (DHMO) to be regulated, labeled as hazardous, or banned, because Dihydrogen monoxide: *is also known as hydroxyl acid, and is the major component of acid rain. *contributes to the "greenhouse effect". *may cause severe burns. *contributes to the erosion of our natural landscape. *accelerates corrosion and rusting of many metals. *may cause electrical failures and decreased effectiveness of automobile brakes. *has been found in excised tumors of terminal cancer patients. Despite the danger, dihydrogen monoxide is often used: *as an industrial solvent and coolant. *in nuclear power plants. *in the production of Styrofoam. *as a fire retardant. *in many forms of cruel animal research. *in the distribution of pesticides. Even after washing, produce remains contaminated by this chemical. *as an additive in certain "junk-foods" and other food products.

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    wwwelkam lol - i may use this in future vids - brilliant lol

  • @replanet2114
    @replanet21148 жыл бұрын

    How do we make the alkali solution?

  • @ThinkingandTinkering

    @ThinkingandTinkering

    8 жыл бұрын

    get some alkali and put it in water You may want to do a bit of reading.

  • @cyprianserapion2022
    @cyprianserapion20229 жыл бұрын

    The first step to film supercapacitor.

  • @ThinkingandTinkering

    @ThinkingandTinkering

    9 жыл бұрын

    could well be