Restore Silver with Electrochemistry 2017

In this video we restore s silver metal coin with electrochemistry.
Old silver is often tarnished by a thin layer of silver sulfide that appears as a brown color. The silver sulfide can be electrochemically converted back into pure silver if a negative potential is applied.
To do this, first make a solution of 200mL water and 20g sodium chloride (salt) with 10g sodium bicarbonate (baking soda). They won't completely dissolve but this is acceptable. Then simply place a silver object in the solution and contact it with a large piece of aluminum foil. In a short time the silver will be restored.
A very cool way to do the same thing is to use a battery. Connect the negative end of the battery to the silver and the positive end to a large electrode, like a copper plate, and dip them both in the solution.
This process occurs due to electrochemical reduction of the silver sulfide to silver.
Related videos:
Restore silver by electrochemistry 2009: • Cool Science: Restore ...
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Пікірлер: 463

  • @NurdRage
    @NurdRage6 жыл бұрын

    Any of my old videos that you think i should redo?

  • @hongbitter7142

    @hongbitter7142

    6 жыл бұрын

    NurdRage do your video on making nitric acid! I loved that one!

  • @user-um9qn3uj4e

    @user-um9qn3uj4e

    6 жыл бұрын

    NurdRage magnetic salts!!!

  • @user-um9qn3uj4e

    @user-um9qn3uj4e

    6 жыл бұрын

    Plz

  • @zock4419

    @zock4419

    6 жыл бұрын

    What about the Hydrazine sulfate one?

  • @agentelement9922

    @agentelement9922

    6 жыл бұрын

    Pyrimethamine! :P

  • @heyyou5801
    @heyyou58014 жыл бұрын

    Just cleaned all of my grandfathers old coins. He will be so pleased.

  • @Dubtee

    @Dubtee

    Жыл бұрын

    Lmao

  • @kevincaywood3830

    @kevincaywood3830

    Жыл бұрын

    😆

  • @CakeZRqGoTR

    @CakeZRqGoTR

    Жыл бұрын

    dread emoji

  • @InssiAjaton
    @InssiAjaton6 жыл бұрын

    My mother once restored her heritage silver spoons, forks and knives by just boiling them in an aluminum kettle, using just a small amount of ordinary (iodized) table salt in also small amount of our quite hard tap water. The silverware had been tarnished due to little use and no protective paper wraps or anything. Previously they had been occasionally cleaned by some mildly abrasive paste, but that was tedious, one piece at a time. Moreover it removed some of the precious silver. This salt and aluminum method was in effect a bulk operation and also did not consume any of the silver.

  • @frotwithdanger
    @frotwithdanger6 жыл бұрын

    That reminds me of when I was a kid watching Mr. Wizard. A dramatic effect explained by science. Bravo!

  • @otmar3840
    @otmar38406 жыл бұрын

    Taking a corrosion course currently, this is so interesting. Cheers, man. Loved it!

  • @WWEdeadman
    @WWEdeadman6 жыл бұрын

    4:35 Moments like that are why I love chemistry. Great video, as usual.

  • @Nyuum
    @Nyuum6 жыл бұрын

    I'm delighted and enlightening by the science. Please don't stop making these types of vids. I really enjoyed it :)

  • @agnosjr
    @agnosjr6 жыл бұрын

    Awesomeness happening before our own eyes! Thank you for sharing it.

  • @alex-9533
    @alex-95336 жыл бұрын

    This is amazing, thanks for all the work you put into your videos!

  • @robotslug
    @robotslug6 жыл бұрын

    That was EXTREMELY cool. I had no idea this was a thing, thank you, as always, for your informative and interesting content!

  • @TheNecropolis20

    @TheNecropolis20

    2 жыл бұрын

    at Robo t Slug - yeah Rob , it was really cool This man has accomplished what the alchemists wanted to do, turn the sulfer into gold or silver... this is done by getting rid of the sulfer from the silver and gold coins.. making them like new is the best way to create valuable silver and gold. if we can market the sulfer or the dirt as intrinsic value then its got more value more value than silver value, but we can pay this for shinny silver or gold coins too.

  • @rakinkazi9780
    @rakinkazi97806 жыл бұрын

    4:38 I can already see this becoming a trending gif

  • @draxxsklounst6595

    @draxxsklounst6595

    6 жыл бұрын

    Lol yup, "over less than 2 seconds" not sure how long that is......

  • @gonebamboo4116
    @gonebamboo41164 жыл бұрын

    Best silver cleaningvideo I've found. Thanks a bunch

  • @DieselDog1929
    @DieselDog19293 жыл бұрын

    Wish you were my chemistry teacher back in the day! I would have had an A+ instead of a B! Love the content, keep the videos coming!! Thanks!

  • @mastrbutcher
    @mastrbutcher6 жыл бұрын

    Love this stuff! TY for taking the time!

  • @alex92569
    @alex925696 жыл бұрын

    That is very educational video. It will also make people better understand why steel does not corrode when coated with zinc layer or in contact with a zinc object. Your example is so fast that it is much easier to observe than slow steel corrosion process.

  • @SeanHodgins
    @SeanHodgins6 жыл бұрын

    Try the reverse, since the electrical potential is -1.66V you're creating a battery with the tarnish and the aluminum. Try illuminating an LED or something similar with the recreation. The current is probably extremely low but you might be able to get it to work.

  • @Theo0x89

    @Theo0x89

    6 жыл бұрын

    Shouldn't the cell voltage be -0.69-(-1.66)=0.97V? That wouldn't be enough to light an LED.

  • @SeanHodgins

    @SeanHodgins

    6 жыл бұрын

    I think he is saying those are two different reactions with two different electrical potentials. So one is 0.69, the other is 1.66, they aren't done at the same time. He used the one with the higher voltage because it works better and is faster for reducing the coin.

  • @mylesbishop1240
    @mylesbishop12406 жыл бұрын

    Wow, this is just amazing. The reaction is so fast.

  • @TheKazzarry
    @TheKazzarry6 жыл бұрын

    Thanks man did this to my mothers silverware set, she was so happy to not be using a rag and buffing compound, did a full set in like 5mins, although she wasnt to happy with the smell of the kitchen afterwards.

  • @curtismiles4221
    @curtismiles42212 жыл бұрын

    Great video,You don,t waste our time and you taught me a lot very quickly.

  • @geodeaholicm4889
    @geodeaholicm48896 жыл бұрын

    very cool demo & explanation.

  • @pietop55
    @pietop556 жыл бұрын

    Wow! I enjoyed this very much!! Thank you for posting.

  • @afiogem
    @afiogem3 жыл бұрын

    OMG Thank you so much for this video. My silver expensive jewellery got very tarnished (turned dark purple bronze colour- was super panicked) in washing powder solution whilst hand washing some soaked clothes. Tried the baking soda solution on foil in a glass bowl with hot water didn't really make a difference.... Started to look online to buy a silver tarnish product. Came across your video followed your salt/ Baking powder instructions within 10 seconds I kid you not, I couldn't believe it. My jewellery is now gleaming...Thank you so much.I will donate to you the cost of the silver product I was seeking to buy online. Thank you.

  • @YEOTTI

    @YEOTTI

    2 жыл бұрын

    What did you do

  • @Hydrogen4Health
    @Hydrogen4Health6 жыл бұрын

    Great experiment. I'll be using this on my silver.

  • @tghost7721
    @tghost7721 Жыл бұрын

    Great presentation! I just subscribed only after the 1st video. Can't wait to see more like this. Thank you

  • @bigpapatronisback
    @bigpapatronisback6 жыл бұрын

    This is great. Well done!

  • @p.f.3014
    @p.f.30146 жыл бұрын

    Thank you! I just cleaned 15 years of black sulphide from our teapot using this method in a bucket. It worked brilliantly while I found I could 'encourage' the process by rubbing the stubborn parts with bicarbonate powder.

  • @NurdRage

    @NurdRage

    6 жыл бұрын

    Awesome! i'm glad it worked for ya :)

  • @p.f.3014

    @p.f.3014

    6 жыл бұрын

    Your videos are great. I look forward to new ones. I'd suggest covering new reactions rather than revisiting the old. Technical discussion of retrosynthesis would be interesting, as would some heterocyclic syntheses.

  • @niclas8591
    @niclas85916 жыл бұрын

    I did this with my kids yesterday. Amazingly easy and fun to watch.

  • @jholland404

    @jholland404

    2 жыл бұрын

    It has been 4 years, have your kids maintained their shiny glow? Or have they begun to tarnish? :)

  • @earthlingjohn

    @earthlingjohn

    Жыл бұрын

    @@jholland404 😂😂😂 Also did they retain their numismatic value ??

  • @user-et8vm9cc3t
    @user-et8vm9cc3t4 жыл бұрын

    Fascinating ! Really fascinating !

  • @UnitSe7en
    @UnitSe7en6 жыл бұрын

    Nice to see you have a (mostly) new stirbar. :D

  • @paulneg7855
    @paulneg78556 жыл бұрын

    I fricken love your channel! Your chemistry is so cool!

  • @mon94key
    @mon94key6 жыл бұрын

    When he wants you to watch it in 4k but you click too early and watch in 360p 😂

  • @jpmvidal
    @jpmvidal6 жыл бұрын

    Great video. It would be great to see a video on copper plating coins of different metals, or perhaps nickel plating or aluminum plating such coins.

  • @Atchitchi
    @Atchitchi6 жыл бұрын

    I just did this experiment today, and it is amazing. I use it to clean some of my wife's expensive toys and it worked so nice. I did a small alteration that did increase the reaction speed, a few seconds on the microwave :D that resulted on a reaction as fast as the electrolisis process

  • @shadowninja1842
    @shadowninja18426 жыл бұрын

    Awesome work! Keep it up!

  • @puddin_orc
    @puddin_orc6 жыл бұрын

    That was very cool, it looked like it was oxidizing the copper in your wires too in the battery example

  • @Jerry-Parker
    @Jerry-Parker10 ай бұрын

    Very Nicely Done ! 👍

  • @hongbitter7142
    @hongbitter71426 жыл бұрын

    Love the videos! You made me love chemistry!

  • @TheMinersMinors
    @TheMinersMinors6 жыл бұрын

    *Watches in 480p anyways* Thanks for the great videos! I've been a loyal subscriber since 2010. Keep it up!

  • @Nocare89
    @Nocare896 жыл бұрын

    I really enjoyed this one.

  • @chrisperyagh
    @chrisperyagh3 жыл бұрын

    Thanks for this, especially 3:57 onwards. If only I'd known about this back in the '80s!

  • @donaldspeck9212
    @donaldspeck921211 ай бұрын

    Please do more videos like this one. Using different chemicals and different metals👍

  • @maxximumb
    @maxximumb6 жыл бұрын

    That was amazing.

  • @leoruotsalainen6339
    @leoruotsalainen63392 жыл бұрын

    Well done 👍👍Great video 👍👍Thanks 👍👍

  • @familybonding9188
    @familybonding91883 жыл бұрын

    Interesting video..Thank you for sharing💖

  • @jagman7023
    @jagman70235 ай бұрын

    Thank you so much for making this video.!!

  • @donnaflannery2757
    @donnaflannery27572 жыл бұрын

    Loved it. Thank you.

  • @danaltaras1095
    @danaltaras10956 жыл бұрын

    Wow, your video was very well done, and more informative than I could handle! Thank you. I've a question that lead me here in the first place, perhaps you could help: I was wondering if something similar would work on a carbon steel knife. Carbon steel oxidizes \ forms a patina when it comes in contact with moisture, and even more so with acidic elements. I've often used baking soda mixed with only a few drops of water as a slurry to rub deeply against the steel and thus remove the patina. Would iron \ steel enjoy the same process that silver does? Perhaps some metal "lower" than aluminum? Did this make sense? Thank you for your help! Dan

  • @oneministries4878
    @oneministries48786 жыл бұрын

    I like it! Good job!!

  • @DrakkarCalethiel
    @DrakkarCalethiel6 жыл бұрын

    Never thought that just two metals​ touching each other would be enough to completely get rid of the tarnish. You always learn new stuff, and the awesome thing is that you get it basically for free. Thanks for sharing! Oh forgot one thing, does someone know how to get rid of rust on iron/high carbon steel caused by hydrochloric acid? Tried polishing and rust removing agents but you can still see the orange/brown stuff caused by the HCl. I would highly appreciate it if someone knows​ how to get rid of it!

  • @attpureownpk
    @attpureownpk6 жыл бұрын

    very cool really enjoyed this!

  • @calebfetveit3508
    @calebfetveit35086 жыл бұрын

    That was awesome!

  • @decoman100
    @decoman1005 жыл бұрын

    amazing video ...thanks

  • @briannolan7818
    @briannolan78182 жыл бұрын

    Great video. So what happens if you leave it to be electrolysized(?) for a long period of time, or even do it 2 or 3 times? Will it improve the look? Thank you,

  • @stcrussman
    @stcrussman6 жыл бұрын

    More electrochemistry please

  • @KorinWeirdKid
    @KorinWeirdKid5 жыл бұрын

    Works great on old Or tarnished jewelry!

  • @alexgratzaTV
    @alexgratzaTV5 жыл бұрын

    amazing video

  • @harshrajkamal3943
    @harshrajkamal39436 жыл бұрын

    Excellent.Keep it up.

  • @johnclavis
    @johnclavis6 жыл бұрын

    That was neat, thanks!

  • @sonicthehedshot9789
    @sonicthehedshot97896 жыл бұрын

    That's some good chem right there.

  • @terenieves5154
    @terenieves51546 жыл бұрын

    That was awsome!

  • @aga5897
    @aga58976 жыл бұрын

    Excellent !

  • @okidokimate1097
    @okidokimate10976 жыл бұрын

    Loved it!

  • @sagerobot
    @sagerobot6 жыл бұрын

    Wow thats really cool!

  • @spaceghostcoasttocoast9343
    @spaceghostcoasttocoast93436 жыл бұрын

    Dopeee love to see you drop a new video. Cool as ice too lol

  • @edmulterer5984
    @edmulterer5984 Жыл бұрын

    This is amazing chemistry in life!!

  • @silverwiskers7371
    @silverwiskers73714 жыл бұрын

    INCREDIBLE

  • @ivan9066
    @ivan90665 жыл бұрын

    Yesterday i was In a mineral bath and my silver pendant stained itself instantly, this vid Will be realy useful.

  • @ngtszyu
    @ngtszyu6 жыл бұрын

    Amazing reaction! I have never expected a electrochemistry happening so fast! I have a question regarding to this reaction though. Are the H2S introduced by yourself, or is it a common contaminant that attacks silver?

  • @desartster71
    @desartster713 жыл бұрын

    Brilliant!

  • @juliemurphy5934
    @juliemurphy59342 жыл бұрын

    Utterly fascinating! I found several silver items in an old well. They are badly crusted with something - not mud or dirt but something that steel wool won't budge. I am going to try this in the hope it might work.

  • @dogwklr

    @dogwklr

    Жыл бұрын

    Did it?

  • @Gmafia76

    @Gmafia76

    10 ай бұрын

    Did it?

  • @GiGaHarrySfotter
    @GiGaHarrySfotter6 жыл бұрын

    really nice!

  • @JW52654
    @JW526542 жыл бұрын

    wow, just awesome, thanks a lot.

  • @Ramakantmumbai
    @Ramakantmumbai4 жыл бұрын

    Superb...

  • @kirtandrews1859
    @kirtandrews18592 жыл бұрын

    Wow just wow. I must own no less than a kilo of heavy solid silver jewellery that I like spotless. And yes you guessed I hate hate polishing cleaning. So going to try this. Thank you

  • @WaschyNumber1
    @WaschyNumber16 жыл бұрын

    Awesome 👍👍👍👍

  • @evilsharkey8954
    @evilsharkey89542 жыл бұрын

    You gotta warn people about the smell! Doing that reaction releases malodorous sulfur compounds. It’s a good experiment to do outside.

  • @Anthony-vj1nu
    @Anthony-vj1nu6 жыл бұрын

    It was taking to long to shine one of my bugles so i tried this though i used a method similar to brush electroplating, Its amazing how fast the reaction was. Instead though i used a 9v battery not a pack

  • @FoxvoxDK
    @FoxvoxDK6 жыл бұрын

    Perhaps a redo of the "Get Lithium from a battery"?

  • @premierflutes9254
    @premierflutes925411 ай бұрын

    This has been a great help for me, in my cleaning of silver plated and solid silver flutes. They have fiddly bits that are hard to reach, and so this method is a great help. I sometimes have a gold plated onto silver area, where tarnishing on the silver below is starting to show through. If I use this method, would it remove the tarnish on the silver below the gold plating, without damaging the gold plating? Thanks

  • @MrAnd3rsson
    @MrAnd3rsson6 жыл бұрын

    Would this work the same for 925 silver? (commonly used in jewelery) or would it have some other kind of reaction since that silver isn't quite so pure?

  • @akhileshchaurasiya815
    @akhileshchaurasiya8152 жыл бұрын

    Awesome👍👍👍👍

  • @PlasmaHH
    @PlasmaHH6 жыл бұрын

    We have been using this to clean silver ever since in our household, but we only used salt, no baking soda and it worked fine too, does the baking soda really make such a big difference?

  • @summerlaverdure
    @summerlaverdure6 жыл бұрын

    OMG that was AMAZING! Science is so cool! ^O^

  • @DocZoda
    @DocZoda6 жыл бұрын

    @NurdRage Were your fluorescent dyes made in 4k? The colors were brilliant nonetheless.

  • @kiraeh
    @kiraeh6 жыл бұрын

    Hey NurdRage! I know nearly nothing about chemistry but I really love watching your videos. I was wondering what gas was being produced by the positive wire going into the solution. Some gas bubbles also formed on the coin itself.

  • @stanjohnson591

    @stanjohnson591

    2 жыл бұрын

    Really neat! Thanks

  • @smulick
    @smulick6 жыл бұрын

    So if you leave the battery setup running in solution for a while, would you end up with a coating of whatever metal the wire is made of (I'm assuming copper) as the anode is oxidized to ions in solution? If so, is there any choice of electrode that'd avoid that?

  • @DoRC
    @DoRC6 жыл бұрын

    I'll gladly re-watch any video you want to make again in high quality!

  • @TheArzonite
    @TheArzonite6 жыл бұрын

    What would happen if you'd keep the silver coin in after there is no silver sulfide left on the coin?

  • @Zendail
    @Zendail6 жыл бұрын

    This was great, does it work with silver utensiles?

  • @pauloavilaneto
    @pauloavilaneto6 жыл бұрын

    pretty cool

  • @stomp4412
    @stomp44126 жыл бұрын

    that was pretty kool

  • @TheTarrMan
    @TheTarrMan6 жыл бұрын

    COOL!

  • @OneOfDisease
    @OneOfDisease6 жыл бұрын

    Would this work the same on metals that were treated with a solution to add tarnish via patina?

  • @ilaril
    @ilaril6 жыл бұрын

    No matter how many times I see that happening, it feels like the first time as a kid seeing the silver clearing in front of your eyes.

  • @adrianocasalmerjr6674
    @adrianocasalmerjr66743 жыл бұрын

    Nice 👍👍👍

  • @Styxblade
    @Styxblade6 жыл бұрын

    He did it, nice.

  • @dsun2625
    @dsun26255 жыл бұрын

    Cool!

  • @randy1817
    @randy18174 жыл бұрын

    Cool!!

  • @alsenkeia2130
    @alsenkeia21306 жыл бұрын

    Does the reaction produces electric current and measure it if we're using copper wire connecting the silver and the aluminum foil rather than making them touch directly?

  • @flinkiandthebrain
    @flinkiandthebrain5 жыл бұрын

    Hi, I was very excited when I watched the video. I work a lot with silver and tried the method with the batteries today. I used a 9 Volt battery and tried it on a spoon. I used cables with crocodile clamps. It was heavily bubbling and the water turned almost black which got me thinking it works for me too. However: The spoon is still dirty but the positively charged crocodile clamp fully dissolved in the water! What did I do wrong if so?