14.2 Rate Laws | General Chemistry

Chad provides a comprehensive lesson on Rate Laws and how to calculate a rate law from a table of kinetic data. The lesson begins with an introduction to what a rate law looks like including the rate constant, k, the reactant orders, and the overall order of reaction. A description of reactant order and the overall order of reaction is provided. The rate of reaction is not affected by the concentration of a zero order reactant. The rate of reaction is proportional to the concentration of a first order reactant. The rate of reaction is proportional to the square of the concentration of a second order reactant. Finally, the overall order of reaction is equal to the sum of the individual reactant orders.
Chad then shows how to calculate the rate law from a table of experimental data. He explains how to recognize which trials to compare to determine a particular reactant's order and then how to perform the calculation. Once all the individual reactant orders have been calculated, he then shows how to calculate the rate constant. Depending upon the overall order of reaction, the unit of the rate constant vary. Chad also shows how to find rate constant units and an easy way to remember the units for each order of reaction.
I've embedded this playlist as a course on my website with all the lessons organized by chapter in a collapsible menu and much of the content from the study guide included on the page. Check this lesson out at www.chadsprep.com/chads-gener...
If you want all my study guides, quizzes, final exam reviews, and practice exams, check out my General Chemistry Master Course (free trial available) at www.chadsprep.com/genchem-you...
00:00 Lesson Introduction
00:42 Rate Laws, Rate Constants, and Reaction Orders
03:21 Zero Order Reactants, 1st Order Reactants, 2nd Order Reactants
09:21 How to Calculate a Rate Law from a Table of Experimental Data
18:30 How to Calculate the Rate Constant
21:20 How to Find Rate Constant Units
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  • @samanthasanchez7098
    @samanthasanchez70984 ай бұрын

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  • @ChadsPrep

    @ChadsPrep

    4 ай бұрын

    Thank you for the kind words - I appreciate your comments. It is gratifying to hear that your understanding is deepening. Happy Studing!

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  • @ChadsPrep

    @ChadsPrep

    2 жыл бұрын

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    @ChadsPrep

    Жыл бұрын

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  • @marisolbravo3929
    @marisolbravo392910 ай бұрын

    9:23 really liked the analogy of the car to understand how to get parcial orders

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    @ChadsPrep

    10 ай бұрын

    Glad you find it helpful.

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    2 жыл бұрын

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    Жыл бұрын

    Glad the video is helping, Andre - Happy Studying!

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    @carapencak950229 күн бұрын

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    @ChadsPrep

    29 күн бұрын

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  • @Patrick.Holland
    @Patrick.Holland4 ай бұрын

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    @ChadsPrep

    4 ай бұрын

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    @ChadsPrep

    2 жыл бұрын

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    5 ай бұрын

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    @sumnerjones858811 ай бұрын

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    @ChadsPrep

    11 ай бұрын

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    @ChadsPrep

    Жыл бұрын

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    @tamer45458 ай бұрын

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    @ChadsPrep

    8 ай бұрын

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    @ChadsPrep

    2 ай бұрын

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  • @lumajohn4647
    @lumajohn4647 Жыл бұрын

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    @ChadsPrep

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    @ChadsPrep

    4 ай бұрын

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    @ChadsPrep

    9 ай бұрын

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  • @ChadsPrep

    @ChadsPrep

    4 ай бұрын

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    @_beautyyofislam2 жыл бұрын

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    @ChadsPrep

    2 жыл бұрын

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    @alessandrac19403 ай бұрын

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  • @ChadsPrep

    @ChadsPrep

    3 ай бұрын

    Glad the channel is helping - Happy Studying!

  • @ss-nu8xx
    @ss-nu8xxАй бұрын

    Wow! Loved the unit of k giving away rate order. So good!!!

  • @ChadsPrep

    @ChadsPrep

    29 күн бұрын

    Thank you!

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    @kristencohen58513 ай бұрын

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  • @ChadsPrep

    @ChadsPrep

    3 ай бұрын

    Thank you and glad the channel is helping you - Happy Studying!

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    @Vickyiyke11 күн бұрын

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    @ChadsPrep

    11 күн бұрын

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    @user-wh7rb6jt7d Жыл бұрын

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    @ChadsPrep

    Жыл бұрын

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  • @AVImid2311
    @AVImid231120 күн бұрын

    Thanks Mr.Chad...From Sri Lanka

  • @ChadsPrep

    @ChadsPrep

    19 күн бұрын

    You're welcome from USA

  • @badejoemmanuel3828
    @badejoemmanuel38286 ай бұрын

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  • @ChadsPrep

    @ChadsPrep

    6 ай бұрын

    Excellent - you are welcome!

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    @manuelachch4 ай бұрын

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  • @ChadsPrep

    @ChadsPrep

    4 ай бұрын

    Glad the channel is helping you - Happy Studying!

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    @courtneyjohnson5529 Жыл бұрын

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  • @ChadsPrep

    @ChadsPrep

    Жыл бұрын

    Thanks and you're welcome - Happy Studying!

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    @yasmeennehad3445Ай бұрын

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    @ChadsPrep

    Ай бұрын

    Glad the channel is helping you

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    @ChadsPrep

    Ай бұрын

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    @shadaane3 ай бұрын

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    @ChadsPrep

    3 ай бұрын

    Thank you very much! To you, also!

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    @user-sy1tx6ud3k5 ай бұрын

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  • @ChadsPrep

    @ChadsPrep

    5 ай бұрын

    You are welcome!

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    @BirManyak.3 ай бұрын

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  • @ChadsPrep

    @ChadsPrep

    3 ай бұрын

    Glad that the channel is helping you and I hope your firstborn is a boy! :-)

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    @TaongaNamukoko13 күн бұрын

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  • @ChadsPrep

    @ChadsPrep

    13 күн бұрын

    Thanks!

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    @johnadamzimba83203 ай бұрын

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    @carolynncalin1199 Жыл бұрын

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    @ChadsPrep

    Жыл бұрын

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    @nohelialovatonaragon4745 Жыл бұрын

    Thank You so much! I was stuck and frustared. Thank you thank you. They should show your videos in online classes honestly, my professors had me so confused and never give good examples to solve my labs. I have a question though, how do you solve when instead of doubling or tripling, they divide, for example, from 0.02 to 0.01, what would be the order?

  • @badteam5500
    @badteam550010 ай бұрын

    Thank you very much god bless you❤

  • @ChadsPrep

    @ChadsPrep

    10 ай бұрын

    You're welcome and Thank You!

  • @lianeslife8061
    @lianeslife80616 ай бұрын

    Thank you! I finally understand

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    @ChadsPrep

    6 ай бұрын

    Awesome :)

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    @zeerah12 жыл бұрын

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    @ChadsPrep

    2 жыл бұрын

    Glad you found the channel, Zeshawn!

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    @zeerah1

    2 жыл бұрын

    @@ChadsPrep Nice to be in touch. I am currently taking Organic Chem 2 and your videos provide extra clarity when reviewing at home

  • @ChadsPrep

    @ChadsPrep

    2 жыл бұрын

    @@zeerah1 Glad to hear it - Happy Studying!

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    @mojolu548 Жыл бұрын

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    @ChadsPrep

    Жыл бұрын

    Hope you do well on your quiz.

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    @nazaninwalizada96054 ай бұрын

    I wish you were my chem professor. Thanks for this great video.

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    @ChadsPrep

    4 ай бұрын

    Thank you!

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    @julietonyekaonwu3107 Жыл бұрын

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    @ChadsPrep

    Жыл бұрын

    You're welcome

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    @savannawilliams93582 жыл бұрын

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    @ChadsPrep

    2 жыл бұрын

    Thanks, Savanna - you as well!

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    @user-yj6dk9bm9x6 ай бұрын

    شكراًجزيلاً🥰

  • @ChadsPrep

    @ChadsPrep

    6 ай бұрын

    You're very welcome!😊

  • @nasiahope-weston5535
    @nasiahope-weston55359 ай бұрын

    Seriously gonna name my first son Chad. Thanks so much :) !

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    @ChadsPrep

    9 ай бұрын

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    @ikomba6631 Жыл бұрын

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    @ChadsPrep

    7 ай бұрын

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    @anita3956Ай бұрын

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    @ChadsPrep

    Ай бұрын

    You're welcome!

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    @ChadsPrep

    Жыл бұрын

    You're welcome.

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    @kienvincent10697 ай бұрын

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    @ChadsPrep

    7 ай бұрын

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    @ChadsPrep

    7 ай бұрын

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    @ryca1236 ай бұрын

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    @ChadsPrep

    6 ай бұрын

    You're welcome!

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    @HasinduGayathra22 күн бұрын

    u r a herooooo!!!!!!!!

  • @ChadsPrep

    @ChadsPrep

    22 күн бұрын

    Thanks - Happy Studying!

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    You are the best

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    @ChadsPrep

    Жыл бұрын

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    @shabisepah24015 ай бұрын

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    @ChadsPrep

    5 ай бұрын

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    @ChadsPrep

    4 ай бұрын

    Glad the channel is helping you.

  • @explaindofficial
    @explaindofficial5 ай бұрын

    Oh my god. I did not understand the lecture at all in my class. I immedietly turned to you and am glad I did. Please do every student a solid and never stop creating. The world is lucky and fortunate to have you. Also could you also make a chem video for easily telling if a molecule is polar without the need to use full vsepr theory and without access to electronegativity numbers becuase in AP Chemistry, you only have the periodic table. Thanks :)

  • @ChadsPrep

    @ChadsPrep

    5 ай бұрын

    Happy to hear the content is helping you! Happy studying :)

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    @user-ch2zv4iz4k8 ай бұрын

    he is a goat indeed👑

  • @ChadsPrep

    @ChadsPrep

    8 ай бұрын

    Happy Studying!

  • @sam17577
    @sam175775 ай бұрын

    i will consider naming my firstborn chad, thank you professor :)

  • @ChadsPrep

    @ChadsPrep

    5 ай бұрын

    Wow - the channel can affect people in all kinds of ways - Glad it is helping you!

  • @ghazalt8870
    @ghazalt8870Ай бұрын

    Thank you for the video. How do you determine the initial rate?

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    @TimothyFernando-yj9wr Жыл бұрын

    Thank u daddy❤

  • @ChadsPrep

    @ChadsPrep

    Жыл бұрын

    Happy Studying.

  • @AdamTheTwinkie
    @AdamTheTwinkie Жыл бұрын

    great great video! the only one I understood infact haha

  • @ChadsPrep

    @ChadsPrep

    Жыл бұрын

    Thanks - glad it helped!

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    @benedictafredrick60034 ай бұрын

    I'd definitely name my firstborn Chad 😂😂❤❤❤❤

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    @ChadsPrep

    4 ай бұрын

    With or without hair will work!!!!

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    @harsh-ub5wl6 ай бұрын

    Lovely 🙏🏾🙏🏾Radhe Krishna bless u🙏🏾❤

  • @ChadsPrep

    @ChadsPrep

    6 ай бұрын

    Welcome to the channel

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    @JesusisK1ng9 Жыл бұрын

    Love the shirt.

  • @ChadsPrep

    @ChadsPrep

    Жыл бұрын

    Thanks.

  • @Sinkalayhuset
    @Sinkalayhuset7 күн бұрын

    Good tutor

  • @ChadsPrep

    @ChadsPrep

    7 күн бұрын

    Thank you

  • @339059331
    @339059331 Жыл бұрын

    struggled for days self-learning, this man used 25 min to kill it!

  • @ChadsPrep

    @ChadsPrep

    Жыл бұрын

    Glad it helped!

  • @BunmiHelen-zt8ui
    @BunmiHelen-zt8ui11 ай бұрын

    That is a nice one sir, but i don't get the table

  • @ikomba6631
    @ikomba6631 Жыл бұрын

    but help us with some video about steam distillation specifically explanation of the conditions for a substance to be steam distilled

  • @leobi1243
    @leobi12433 ай бұрын

    I have a question here, so the rate we calculated is the rate of change in concentration of Cl2 or NO? As I understand it, the rate for NO is double that of Cl2 because of NO's coefficient, so what is the reaction rate representing here?

  • @ChadsPrep

    @ChadsPrep

    3 ай бұрын

    Hi Leo! If you look back at the previous video in the playlist, I introduce rate expressions and explain that the rate of reaction can be expressed in terms of any reactant or product. The absolute value of the rate of reaction will be the same as the rate of change for a reactant or product with a coefficient of 1, half the absolute value of the rate of change for a reactant/product with a coefficient of 2, one-third of the absolute value of the rate of change for a reactant/product with a coefficient of 3, etc. This way, regardless of which reactant or product you consider, the overall rate of reaction will have the same value. Hope this helps!

  • @zacharypritchett2206
    @zacharypritchett22062 жыл бұрын

    Hey Chad, what if the concentration from trial one to trial two in NO decreased, but stayed constant in Cl2? would the exponent be a fraction?

  • @ChadsPrep

    @ChadsPrep

    2 жыл бұрын

    Hey Zachary - yes we would end up with a fractional exponent in that case. BUT! if the NO concentration halved and the rate halved also it would still be first order :)

  • @AnonymousGUY554
    @AnonymousGUY55411 ай бұрын

    Hello sir, I have a question on my book where 2 concentrations are given and one of the concentration is not constant. Can u please help me with that.

  • @austincox1758
    @austincox1758 Жыл бұрын

    my beautiful friend, you've done it again

  • @ChadsPrep

    @ChadsPrep

    Жыл бұрын

    Glad to hear it A.C. - thanks for saying so!

  • @user-ju6kf1tt6q
    @user-ju6kf1tt6q4 ай бұрын

    How do you know the trial to pick what concept do you use

  • @ChadsPrep

    @ChadsPrep

    4 ай бұрын

    It is always easier to pick a pair of trials to compare where only the concentration of one reactant is changed if possible.

  • @krgod3644
    @krgod36442 жыл бұрын

    The rate we get in rate laws is inital rate?

  • @peybak

    @peybak

    2 жыл бұрын

    Yes, because if you let a reaction go, it might reach equilibrium. So they usually just measure the initial rate.

  • @JESUS-IS-GOD316
    @JESUS-IS-GOD3166 ай бұрын

    Wow. Great lesson. I love your shirt. God bless you. I pray that for helping us may God bless you massively. Eternal life with Christ is my prayer for you Prof❤Amen.

  • @ChadsPrep

    @ChadsPrep

    6 ай бұрын

    Thank you so much and right back at you 🙏

  • @shadaane
    @shadaane3 ай бұрын

    My first born boy will definitely be a Chad. My name is Shadane and people call me Shad 😂❤ seriously!

  • @ChadsPrep

    @ChadsPrep

    3 ай бұрын

    Shad with son Chad - it works! I wish you many blessings with many children, at least one that is a son!

  • @marielle6673
    @marielle66736 ай бұрын

    How do I find those list of numbers you have? The numbers: 0.1 0.1 0.18 0.1 0.2 0.36 0.2 0.2 1.44

  • @shadaane

    @shadaane

    3 ай бұрын

    From experiments. They’re experimental values.

  • @adamk3568
    @adamk3568 Жыл бұрын

    I know what's wrong wit it. It ain't got no gas innet. Anyways thank you for being better than my professor. I learn more from you in 20 min than a semesters worth of class

  • @ChadsPrep

    @ChadsPrep

    Жыл бұрын

    Glad the videos are helping you Adam!

  • @emily191
    @emily1912 жыл бұрын

    I get everything but I’m super confused when it comes to scientific notation. Every time I try to divide it gives me a scientific notation number, not a regular whole number, then I don’t know how to put that decimal to equal a power. Can you please help?

  • @ChadsPrep

    @ChadsPrep

    2 жыл бұрын

    Hey Jayooni - is this on your calculator? Can you give me an example of what you are trying to convert?

  • @emily191

    @emily191

    2 жыл бұрын

    @@ChadsPrep yes it is-- it’s a little hard to send the table over. Is it fine if I email it to you?

  • @emily191

    @emily191

    2 жыл бұрын

    @@ChadsPrep but I’m trying to divide 7.0x10^-4 and 2.8x10^-3 Thanks so much for your response I appreciate it a lot!

  • @josphellihsilak4588

    @josphellihsilak4588

    Жыл бұрын

    @@emily191 This is late, but maybe for someone else needing the same help. Remember an exponent in the denominator can be raised to the numerator by flipping the sign. So I always tell people, in the example you gave, divide the front numbers alone 7/2.8 = 2.5 then flip the exponent in the denominator which pushes it to the numerator (10^-4/10^-3) becomes (10^-4 × 10^3). Multiplying exponents means you add the exponents which now gives you 10^(-4+3) = 10^-1. Now combine it all..2.5 x 10^-1 or .25. Hope that's useful for whomever may need it.

  • @emily191

    @emily191

    Жыл бұрын

    @@josphellihsilak4588 thank you for your response! I ended up asking my brother and he figured it out in less than a minute lol. You can imagine the look on my face haha

  • @sarahtamayo435
    @sarahtamayo435Ай бұрын

    I will be naming my firstborn Chad for you

  • @ChadsPrep

    @ChadsPrep

    Ай бұрын

    Excellent - I wish for him a full head of hair!

  • @charnaeholmes2229
    @charnaeholmes2229 Жыл бұрын

    If i do well only the gen chem portion of my DAT, I WILL BE NAMING my first born CHAD. It was already on my list. It was meant to be

  • @ChadsPrep

    @ChadsPrep

    Жыл бұрын

    Happy Studying.

  • @inayat8503
    @inayat85037 күн бұрын

    👌🏻👌🏻👌🏻

  • @ChadsPrep

    @ChadsPrep

    7 күн бұрын

    Thanks!

  • @LifeUpgrade195
    @LifeUpgrade195 Жыл бұрын

    ''Consider naming your first born Chad" 🤣🤣🤣

  • @ChadsPrep

    @ChadsPrep

    Жыл бұрын

    😁😁😁

  • @eilianejad9178
    @eilianejad9178 Жыл бұрын

    You are not chad you are gigachad.

  • @ChadsPrep

    @ChadsPrep

    Жыл бұрын

    Thanks - glad the channel is helping you!

  • @roroh9818
    @roroh9818 Жыл бұрын

    I watched so many videos, and can understand only yours. 🤣

  • @ChadsPrep

    @ChadsPrep

    Жыл бұрын

    Glad you found us, Roro H!

  • @user-ve1qw4df1i
    @user-ve1qw4df1iАй бұрын

    Am naming m y child Chad 🤣🤣🤣🤣 thank you we'll explained

  • @ChadsPrep

    @ChadsPrep

    Ай бұрын

    Excellent!

  • @kavinduperamuna1494
    @kavinduperamuna1494 Жыл бұрын

    Fucking legend.

  • @ChadsPrep

    @ChadsPrep

    Жыл бұрын

    Glad the video helped!

  • @Jerlogan1191
    @Jerlogan11915 ай бұрын

    I don't know how he got the m-² s-¹. can someone explain pls.

  • @ChadsPrep

    @ChadsPrep

    5 ай бұрын

    So we have (0.18M.s^-1)/[(0.1M^2)(0.1M)]..... just looking at the unit that gives us: (M.s^-1)/[(M^2)(M)].... anything that is on the top and bottom we can cross out.... (-M-.s^-1)/[(M^2)(-M-)] which just leaves us with s^-1 on the top and M^2 on the bottom which is M^-2 s^-1

  • @Jerlogan1191

    @Jerlogan1191

    4 ай бұрын

    @@ChadsPrep thanks prof chad!🙌

  • @ChadsPrep

    @ChadsPrep

    4 ай бұрын

    @@Jerlogan1191 Most welcome.

  • @kalebbeley4687
    @kalebbeley4687Ай бұрын

    Are you a born again ✝️